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Lithium chloride (data page)

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Chemical data page

This page provides supplementary chemical data on Lithium chloride.

Solubility

Solubility of LiCl in various solvents
(g LiCl / 100g of solvent at 25 °C)
H2O 84.5
Liquid ammonia 3.02
Liquid sulfur dioxide 0.012
Methanol 21 - 41
Formic acid 27.5
Sulfolane 1.5
Acetonitrile 0.14
Acetone 0.83
Formamide 28.2
Dimethylformamide 11 - 28
Reference:
Burgess, J. Metal Ions in Solution
(Ellis Horwood, New York, 1978)
ISBN 0-85312-027-7

Thermodynamic properties

Phase behavior
Triple point ? K (? °C), ? Pa
Critical point ? K (? °C), ? Pa
Std enthalpy
of fusionΔfusH 		+19.9 kJ/mol
Std entropy
of fusionΔfusS 		? J/(mol·K)
Std enthalpy
of vaporizationΔvapH 		? kJ/mol
Std entropy
of vaporizationΔvapS 		? J/(mol·K)
Solid properties
Std enthalpy
of formation ΔfHsolid 		−408.27 kJ/mol
Standard molar entropy
Ssolid 		59.33 J/(mol K)
Heat capacity cp 47.99 J/(mol K)
Liquid properties
Std enthalpy
of formation ΔfHliquid 		−390.76 kJ/mol
Standard molar entropy
Sliquid 		? J/(mol K)
Heat capacity cp ? J/(mol K)
Gas properties
Std enthalpy
of formation ΔfHgas 		−195.2 kJ/mol
Standard molar entropy
Sgas 		212.7 J/(mol K)
Heat capacity cp 33.2 J/(mol K)

Spectral data

UV-Vis
Lambda-max ? nm
Extinction coefficient ?
IR
Major absorption bands ? cm
NMR
Proton NMR
Carbon-13 NMR
Other NMR data
MS
Masses of
main fragments

Structure and properties data

Structure and properties
Index of refraction 1.662
Dielectric constant ? C/(N·m) at ? °C
Bond strength ?
Bond length ?
Magnetic susceptibility -24.3 cgs units

Temperature Relative Humidity over saturated solution in water

Temperature(C) Relative Humidity(%)
0.23 14.7
9.56 13.4
19.22 12.4
29.64 11.8
39.64 11.8
46.76 11.4

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions.

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References

  1. Arnold, Wexler (1954). "Relative Humidity-Temperature Relationships of Some Saturated Salt Solutions in the Temperature Range 0 0 to 500 C". Journal of Research of the National Bureau of Standards. 53 (1): 19. doi:10.6028/jres.053.003.
  • Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD)
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