Misplaced Pages

MOF-5

Article snapshot taken from Wikipedia with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
Unit cell structure of MOF-5. The yellow sphere represents the volume of the pore. Oxygen in red, carbon in black, and hydrogen in white. Tetrahedrons represent the coordination of BDC to the Zinc center

MOF-5 or IRMOF-1 is a cubic metal–organic framework compound with the formula Zn4O(BDC)3, where BDC = 1,4-benzodicarboxylate (MOF-5). It was first synthesized by graduate students and post doctoral scholars in the lab of Omar M. Yaghi. MOF-5 is notable for exhibiting one of the highest surface area to volume ratios among metal–organic frameworks, at 2200 m/cm. Additionally, it was the first metal–organic framework studied for hydrogen gas storage.

References

  1. ^ Rosi, Nathaniel L.; Eckert, Juergen; Eddaoudi, Mohamed; Vodak, David T.; Kim, Jaheon; O'Keefe, Michael; Yaghi, Omar M. (2003). "Hydrogen storage in microporous metal-organic frameworks". Science. 300 (5622): 1127–1129. Bibcode:2003Sci...300.1127R. doi:10.1126/science.1083440. PMID 12750515.
  2. ^ Furukawa, Hiroyasu; Cordova, Kyle; Michael, O'Keeffe; Omar, Yaghi (30 August 2013). "The Chemistry and Applications of Metal-Organic Frameworks". Science. 341 (6149): 974. doi:10.1126/science.1230444.
Metal–organic frameworks (MOF)
Carboxylate–based MOFsHKUST-1, MOF-5, MIL-53, DUT-5
Zirconium-based MOFsUIO-66, UiO-67
Nickel-based MOFsNi(ina)2, Ni(3-ain)2, Ni(2-ain)2, Ni(pba)2
Aluminium-based MOFsMIL-53, DUT-5
Azolate-based MOFsMFU-4l, NU-2100
Vanadium-based MOFsCOMOC-2
Molybdenum-based MOFsTUDMOF-1
Zeolitic imidazolate frameworksZIF-8


Stub icon

This article about materials science is a stub. You can help Misplaced Pages by expanding it.

Categories: