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Mercury(II) stearate

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Mercury(II) stearate
Names
Other names Mercuric stearate, mercury distearate, mercury dioctadecanoate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.010.418 Edit this at Wikidata
EC Number
  • 211-458-8
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/2C18H36O2.Hg/c2*1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20;/h2*2-17H2,1H3,(H,19,20);/q;;+2/p-2Key: RRFMRVBJWLMSAB-UHFFFAOYSA-L
SMILES
  • CCCCCCCCCCCCCCCCCC(=O).CCCCCCCCCCCCCCCCCC(=O).
Properties
Chemical formula C
36H
70HgO
4
Molar mass 767.529
Appearance yellow wax
Melting point 112.2 °C (234.0 °F; 385.3 K)
Boiling point 359.4 °C (678.9 °F; 632.5 K)
Solubility in water insoluble
Solubility Soluble in fatty oils
Hazards
Flash point 162.4 °C (324.3 °F; 435.5 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Mercury(II) stearate is a metal-organic compound, a salt of mercury and stearic acid with the chemical formula C
36H
70HgO
4. The compound is classified as a metallic soap, i.e. a metal derivative of a fatty acid. The compound is highly toxic by inhalation, ingestion, and skin absorption.

Synthesis

An exchange reaction of sodium stearate and mercury dichloride:

H g C l 2 + 2 C 17 H 35 C O O N a     H g ( C 17 H 35 C O O ) 2 + 2 N a C l {\displaystyle {\mathsf {HgCl_{2}+2C_{17}H_{35}COONa\ {\xrightarrow {}}\ Hg(C_{17}H_{35}COO)_{2}\downarrow +2NaCl}}}

Also, heating mercurious oxide with stearic acid.

Physical properties

The compound forms yellow waxy substance.

Uses

It is used as a germicide and as a plasticizer in the production of ceramics.

References

  1. ^ Lewis, Robert A. (1 April 2016). Hawley's Condensed Chemical Dictionary. John Wiley & Sons. p. 878. ISBN 978-1-119-26784-3. Retrieved 15 February 2023.
  2. "CAS 645-99-8 Mercury stearate - Alfa Chemistry". alfa-chemistry.com. Retrieved 15 February 2023.
  3. Works of the Cavendish Society: Gmelin, Leopold. Hand-book of chemistry. 18 v. & index. 1848-72. 1866. p. 112. Retrieved 15 February 2023.
  4. Morris, Christopher G.; Press, Academic; Morris, Christopher W. (27 August 1992). Academic Press Dictionary of Science and Technology. Gulf Professional Publishing. p. 1350. ISBN 978-0-12-200400-1. Retrieved 15 February 2023.
Mercury compounds
Mercury(I)
Mercury(II)
Organomercury
compounds
Mercury(IV)
Amalgams
Mercury cations
Salts and covalent derivatives of the stearate ion
HCH3(CH2)16CO2 He
LiCH3(CH2)16CO2 Be(CH3(CH2)16CO2)2 B(CH3(CH2)16CO2)3 C NH4CH3(CH2)16CO2, -O- F Ne
NaCH3(CH2)16CO2 Mg(CH3(CH2)16CO2)2 Al(CH3(CH2)16CO2)3 Si(CH3(CH2)16CO2)4 P(CH3(CH2)16CO2)3 S Cl Ar
KCH3(CH2)16CO2 Ca(CH3(CH2)16CO2)2 Sc(CH3(CH2)16CO2)3 Ti V Cr(CH3(CH2)16CO2)2 Mn Fe(CH3(CH2)16CO2)2
Fe(CH3(CH2)16CO2)3
Co(CH3(CH2)16CO2)2 Ni(CH3(CH2)16CO2)2 Cu(CH3(CH2)16CO2)2 Zn(CH3(CH2)16CO2)2 Ga(CH3(CH2)16CO2)3 Ge As(CH3(CH2)16CO2)3 Se Br Kr
RbCH3(CH2)16CO2 Sr(CH3(CH2)16CO2)2 Y(CH3(CH2)16CO2)3 Zr(CH3(CH2)16CO2)3 Nb Mo Tc Ru Rh Pd(CH3(CH2)16CO2)2 AgCH3(CH2)16CO2 Cd(CH3(CH2)16CO2)2 In(CH3(CH2)16CO2)3 Sn Sb(CH3(CH2)16CO2)3 Te I Xe
CsCH3(CH2)16CO2 Ba(CH3(CH2)16CO2)2 * Lu(CH3(CH2)16CO2)3 Hf Ta W Re Os Ir Pt AuCH3(CH2)16CO2 Hg2(CH3(CH2)16CO2)2,
Hg(CH3(CH2)16CO2)2
TlCH3(CH2)16CO2 Pb(CH3(CH2)16CO2)2 Bi(CH3(CH2)16CO2)3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(CH3(CH2)16CO2)3 Ce(CH3(CH2)16CO2)3 Pr Nd Pm Sm(CH3(CH2)16CO2)3 Eu(CH3(CH2)16CO2)3 Gd(CH3(CH2)16CO2)3 Tb Dy(CH3(CH2)16CO2)3 Ho(CH3(CH2)16CO2)3 Er Tm Yb(CH3(CH2)16CO2)3
** Ac(CH3(CH2)16CO2)3 Th(CH3(CH2)16CO2)4 Pa UO2(CH3(CH2)16CO2)2 Np Pu Am Cm Bk Cf Es Fm Md No
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