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Methanesulfonate monooxygenase

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Class of enzymes
Methanesulfonate monooxygenase
Identifiers
EC no.1.14.13.111
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Methanesulfonate monooxygenase (EC 1.14.13.111, mesylate monooxygenase, mesylate,reduced-FMN:oxygen oxidoreductase, MsmABCD, methanesulfonic acid monooxygenase, MSA monooxygenase, MSAMO) is an enzyme with systematic name methanesulfonate,NADH:oxygen oxidoreductase. This enzyme catalyses the following chemical reaction

methanesulfonate + NADH + H + O2 {\displaystyle \rightleftharpoons } formaldehyde + NAD + sulfite + H2O

Methanesulfonate monooxygenase is a flavoprotein.

References

  1. de Marco P, Moradas-Ferreira P, Higgins TP, McDonald I, Kenna EM, Murrell JC (April 1999). "Molecular analysis of a novel methanesulfonic acid monooxygenase from the methylotroph Methylosulfonomonas methylovora". Journal of Bacteriology. 181 (7): 2244–51. PMC 93639. PMID 10094704.
  2. Higgins TP, Davey M, Trickett J, Kelly DP, Murrell JC (February 1996). "Metabolism of methanesulfonic acid involves a multicomponent monooxygenase enzyme". Microbiology. 142 ( Pt 2): 251–60. doi:10.1099/13500872-142-2-251. PMID 8932698.

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Oxidoreductases: dioxygenases, including steroid hydroxylases (EC 1.14)
1.14.11: 2-oxoglutarate
1.14.13: NADH or NADPH
1.14.14: reduced flavin or flavoprotein
1.14.15: reduced iron–sulfur protein
1.14.16: reduced pteridine (BH4 dependent)
1.14.17: reduced ascorbate
1.14.18-19: other
1.14.99 - miscellaneous
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