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Triphenylphosphine selenide

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(Redirected from Phosphine selenide)
Triphenylphosphine selenide
Names
Preferred IUPAC name Triphenyl-λ-phosphaneselone
Other names triphenylphosphane selenide
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.021.279 Edit this at Wikidata
EC Number
  • 223-406-1
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C18H15PSe/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15HKey: ZFVJLNKVUKIPPI-UHFFFAOYSA-N
SMILES
  • c1ccc(cc1)P(=)(c2ccccc2)c3ccccc3
Properties
Chemical formula C18H15PSe
Molar mass 341.25
Appearance white solid
Melting point 186.5 to 187.5
Solubility in water insoluble
Solubility very soluble in dichloromethane, pyridine, and THF; moderately soluble on heating in acetonitrile, ethanol, and methanol; insoluble in ether
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Triphenylphosphine selenide is an organophosphorus compound with the formula (C6H5)3PSe. It is a white solid which is soluble in most organic solvents. The compound is used in the preparation of other selenium compounds and is itself prepared by the reaction of triphenylphosphine with potassium selenocyanate. Single crystals have been isolated with both monoclinic and triclinic structures (space groups: P21/c and P1 respectively); in both cases the geometry at phosphorus is tetrahedral.

See also

References

  1. Mayhew, D. L., Clive, D. L. J., Stawinski, J. and Bollmark, M. 2004. Triphenylphosphine Selenide. e-EROS Encyclopedia of Reagents for Organic Synthesis doi:10.1002/047084289X.rt378.pub2
  2. Philip Nicpon, Devon W. Meek "Triphenylphosphine Selenide" Inorganic Syntheses, 1967, Volume 10, 157–159. doi:10.1002/9780470132418.ch23
  3. Codding, P. W.; Kerr, K. A. (15 May 1979). "Triphenylphosphine selenide". Acta Crystallographica Section B. 35 (5): 1261–1263. Bibcode:1979AcCrB..35.1261C. doi:10.1107/S0567740879006129.
  4. Jones, P. G.; Kienitz, C.; Thöne, C. (January 1994). "Crystal structure of triphenylphosphine selenide (triclinic), C18H15PSe". Zeitschrift für Kristallographie. 209 (1): 80–81. Bibcode:1994ZK....209...80J. doi:10.1524/zkri.1994.209.1.80.
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