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Silver bromate

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Silver bromate
Names
Systematic IUPAC name Silver(I) bromate
Other names Argentous bromate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.120 Edit this at Wikidata
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/Ag.BrHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1Key: XQLMNMQWVCXIKR-UHFFFAOYSA-M
  • InChI=1/Ag.BrHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1Key: XQLMNMQWVCXIKR-REWHXWOFAZ
SMILES
  • .Br(=O)=O
Properties
Chemical formula AgBrO3
Molar mass 235.770 g/mol
Appearance white powder
photosensitive
Density 5.206 g/cm
Melting point 309 °C (588 °F; 582 K)
Solubility in water 0.167 g/100 mL
Solubility product (Ksp) 5.38×10
Solubility in ammonium hydroxide soluble
Hazards
GHS labelling:
Pictograms GHS03: Oxidizing GHS07: Exclamation mark
Signal word Danger
Hazard statements H272, H315, H319, H335
Precautionary statements P210, P220, P261, P264, P271, P280, P302+P352, P304+P340+P312, P305+P351+P338, P332+P313, P337+P313, P362+P364, P370+P378, P403+P233, P405, P501
Safety data sheet (SDS) MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). ☒N verify (what is  ?) Infobox references
Chemical compound
Silver bromide GIF

Silver bromate (AgBrO3), is a toxic, light and heat-sensitive, white powder.

Uses

Silver bromate can be used as an oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds.

References

  1. John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 978-1138561632.
  2. Perry, Dale L. (2011). Handbook of inorganic compounds (2nd ed.). Boca Raton: Taylor & Francis. p. 365. ISBN 978-1-4398-1461-1. OCLC 587104373.
  3. Mohammadpoor-Baltork, Iraj; Nourozi, Ali Reza (1999). "Efficient and Selective Oxidative Deprotection of Tetrahydropyranyl Ethers, Ethylene Acetals and Ketals with Silver and Sodium Bromates in the Presence of Aluminum Chloride". Synthesis. 1999 (3): 487–490. doi:10.1055/s-1999-3410. S2CID 196725503.

External links

Silver compounds
Silver(0,I)
Silver(I)
Organosilver(I) compounds
  • AgC2H3O2
  • AgC22H43O2
  • CH3CH(OH)COOAg
  • C
    18H
    36AgO
    2
  • AgC4H3N2NSO2C6H4NH2
  • AgC
    11H
    23COO
    • Silver(II)
    Silver(III)
    Silver(I,III)
    Compounds containing the bromate group
    HBrO3 He
    Li Be B C N O F Ne
    NaBrO3 Mg Al Si P S Cl Ar
    KBrO3 Ca(BrO3)2 Sc(BrO3)3 Ti V Cr Mn(BrO3)2 Fe(BrO3)3 Co(BrO3)2 Ni(BrO3)2 Cu(BrO3)2 Zn(BrO3)2 Ga Ge As Se Br2O3
    Br2O5     		Kr
    RbBrO3 Sr(BrO3)2 Y(BrO3)3 Zr Nb Mo Tc Ru Rh Pd AgBrO3 Cd In Sn Sb Te I Xe
    Cs Ba(BrO3)2 * Lu(BrO3)3 Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * La(BrO3)3 Ce(BrO3)3 Pr(BrO3)3 Nd(BrO3)3 Pm(BrO3)3 Sm(BrO3)3 Eu(BrO3)3 Gd(BrO3)3 Tb(BrO3)3 Dy(BrO3)3 Ho(BrO3)3 Er(BrO3)3 Tm(BrO3)3 Yb(BrO3)3
    ** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No


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