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{{chembox {{Chembox
| Verifiedfields = changed
⚫ | verifiedrevid = 385577534
| Watchedfields = changed
⚫ | verifiedrevid = 428743523
| IUPACName = Potassium hydrosulfide | IUPACName = Potassium hydrosulfide
| ImageFile = Sodium-hydrosulfide-LT-xtal-1991-CM-3D-balls.png | ImageFile = Sodium-hydrosulfide-LT-xtal-1991-CM-3D-balls.png
| ImageSize = 250 | ImageSize = 250
| OtherNames = Potassium bisulfide, Potassium sulfhydrate, potassium hydrogen sulfide | OtherNames = Potassium bisulfide, Potassium sulfhydrate, potassium hydrogen sulfide
| Section1 = {{Chembox Identifiers |Section1={{Chembox Identifiers
⚫ | CASNo_Ref = {{cascite|correct|??}}
| CASNo = 1310-61-8 | CASNo = 1310-61-8
⚫ | CASNo_Ref = {{cascite}}
| CASOther = | CASNoOther =
| UNII_Ref = {{fdacite|correct|FDA}}
⚫ | InChI =
| UNII = SX1L03AL9I
| InChIKey =
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = | PubChem = 102109
| PubChem = 102109 | RTECS =
| RTECS = | EINECS = 215-182-9
| EINECS = | ChemSpiderID = 92246
| InChI = 1/K.H2S/h;1H2/q+1;/p-1
⚫ }}
| InChIKey = ZOCLAPYLSUCOGI-REWHXWOFAJ
⚫ | Section2 = {{Chembox Properties
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
⚫ | Formula = HKS
| StdInChI = 1S/K.H2S/h;1H2/q+1;/p-1
⚫ | MolarMass = 72.171 g/mol
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
⚫ | Appearance = white solid
| StdInChIKey = ZOCLAPYLSUCOGI-UHFFFAOYSA-M
⚫ | Density = 1.68–1.70 g/cm<sup>3</sup>
| SMILES = .
| Solubility = good
⚫ }}
| MeltingPt = 455 ºC
⚫ |Section2={{Chembox Properties
| BoilingPt =
⚫ | Formula = KSH
⚫ }}
⚫ | MolarMass = 72.171 g/mol
⚫ | Section7 = {{Chembox Hazards
⚫ | Appearance = white solid
| ExternalMSDS =
⚫ | Density = 1.68–1.70 g/cm<sup>3</sup>
| EUIndex = Not listed
| EUClass = | Solubility = good
| RPhrases = | MeltingPtC = 455
| SPhrases = | BoilingPt =
⚫ }}
⚫ | MainHazards = Flammable solid, stench, releases ]
⚫ |Section7={{Chembox Hazards
⚫ | NFPA-H = 3
| NFPA-F = 2 | ExternalSDS =
| NFPA-R = 0 | HPhrases =
| NFPA-O = | PPhrases =
| FlashPt = | GHS_ref =
⚫ | MainHazards = Flammable solid, stench, releases ]
⚫ }}
⚫ | NFPA-H = 3
⚫ | Section8 = {{Chembox Related
| NFPA-F = 2
⚫ | OtherAnions = ]
| NFPA-R = 0
⚫ | OtherCations = ]
⚫ | NFPA-S =
⚫ | OtherCpds = ]
| FlashPt =
⚫ }}
⚫ }}
⚫ |Section8={{Chembox Related
⚫ | OtherAnions = ]
⚫ | OtherCations = ]
⚫ | OtherCompounds = ]
⚫ }}
}} }}
'''Potassium hydrosulfide''' is the ] with the formula KHS. This colourless ] consists of the cation K<sup>+</sup> and the ] anion <sup>−</sup>. It is the product of the half-neutralization of ] with ]. The compound is used in the synthesis of some ]s.<ref>Dittmer, D. C. “Potassium Hydrogen Sulfide” in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. {{DOI| 10.1002/047084289}}.</ref> It is prepared by neutralizing aqueous KOH with H<sub>2</sub>S.<ref>Kurzer, F. Lawson, A. “Thiobenzoylthioglycolic Acid” Organic Syntheses, Collected Volume 5, p.1046 (1973). </ref> Aqueous solutions of ] consist of a mixture of potassium hydrosulfide and ]. '''Potassium hydrosulfide''' is an ] with the formula KSH. This colourless ] consists of the cation {{chem2|K+}} and the ] anion {{chem2|−}}. It is the product of the half-neutralization of ] with ]. The compound is used in the synthesis of some ]s.<ref>{{cite encyclopedia|author=Dittmer, Donald C.|chapter = Potassium Hydrogen Sulfide | encyclopedia = Encyclopedia of Reagents for Organic Synthesis | editor = Paquette, L. | publisher = J. Wiley & Sons, New York | year = 2001 | doi = 10.1002/047084289X.rp227|isbn = 0471936235 }}</ref> Aqueous solutions of ] consist of a mixture of potassium hydrosulfide and ].


The structure of the potassium hydrosulfide resembles that for ]. Their structure is however complicated by the non-spherical symmetry of the SH<sup>−</sup> ]s, but these tumble rapidly in the solid high temperatures.<ref>{{cite journal | author = Haarmann, F; Jacobs, H.; Roessler, E.; Senker, J. | title = Dynamics of Anions and Cations in Hydrogensulfides of Alkali Metals (NaHS, KHS, RbHS): A Proton Nuclear Magnetic Resonance Study | journal = Journal of Chemical Physics | year = 2002 | volume = 117 | issue = 3 | pages = 1269–1276 | doi = 10.1063/1.1483860}}</ref> The structure of the potassium hydrosulfide resembles that of ]. Their structure is however complicated by the non-spherical symmetry of the {{chem2|SH−}} ]s, but these tumble rapidly in the solid.<ref>{{cite journal |author1=Haarmann, F |author2=Jacobs, H. |author3=Roessler, E. |author4=Senker, J. | title = Dynamics of Anions and Cations in Hydrogensulfides of Alkali Metals (NaHS, KHS, RbHS): A Proton Nuclear Magnetic Resonance Study | journal = Journal of Chemical Physics | year = 2002 | volume = 117 | issue = 3 | pages = 1269–1276 | doi = 10.1063/1.1483860|bibcode=2002JChPh.117.1269H | doi-access = free }}</ref>

The addition of sulfur gives ].

==Synthesis==
It is prepared by neutralizing aqueous ] with ].<ref>{{OrgSynth|prep=CV5P1046|author1=Kurzer, F.|author2=Lawson, A.|title=Thiobenzoylthioglycolic Acid|year=1962|volume=42|page=100|doi=10.15227/orgsyn.042.0100}}</ref><ref>{{cite journal |doi=10.15227/orgsyn.028.0016|title=Benzoyl Disulfide |author=Robert L. Frank and James R. Blegen|journal=Organic Syntheses |year=1948 |volume=28 |page=16 }}</ref>


==References== ==References==
{{reflist}} {{reflist}}


] {{Potassium compounds}}
⚫ ]


]
]
⚫ ]
]

Latest revision as of 05:21, 26 June 2024

Potassium hydrosulfide
Names
IUPAC name Potassium hydrosulfide
Other names Potassium bisulfide, Potassium sulfhydrate, potassium hydrogen sulfide
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.803 Edit this at Wikidata
EC Number
  • 215-182-9
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/K.H2S/h;1H2/q+1;/p-1Key: ZOCLAPYLSUCOGI-UHFFFAOYSA-M
  • InChI=1/K.H2S/h;1H2/q+1;/p-1Key: ZOCLAPYLSUCOGI-REWHXWOFAJ
SMILES
  • .
Properties
Chemical formula KSH
Molar mass 72.171 g/mol
Appearance white solid
Density 1.68–1.70 g/cm
Melting point 455 °C (851 °F; 728 K)
Solubility in water good
Hazards
Occupational safety and health (OHS/OSH):
Main hazards Flammable solid, stench, releases hydrogen sulfide
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g. diesel fuelInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
3 2 0
Related compounds
Other anions Potassium hydroxide
Other cations Sodium hydrosulfide
Related compounds potassium sulfide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). ☒N verify (what is  ?) Infobox references
Chemical compound

Potassium hydrosulfide is an inorganic compound with the formula KSH. This colourless salt consists of the cation K and the bisulfide anion [SH]. It is the product of the half-neutralization of hydrogen sulfide with potassium hydroxide. The compound is used in the synthesis of some organosulfur compounds. Aqueous solutions of potassium sulfide consist of a mixture of potassium hydrosulfide and potassium hydroxide.

The structure of the potassium hydrosulfide resembles that of potassium chloride. Their structure is however complicated by the non-spherical symmetry of the SH anions, but these tumble rapidly in the solid.

The addition of sulfur gives dipotassium pentasulfide.

Synthesis

It is prepared by neutralizing aqueous KOH with H2S.

References

  1. Dittmer, Donald C. (2001). "Potassium Hydrogen Sulfide". In Paquette, L. (ed.). Encyclopedia of Reagents for Organic Synthesis. J. Wiley & Sons, New York. doi:10.1002/047084289X.rp227. ISBN 0471936235.
  2. Haarmann, F; Jacobs, H.; Roessler, E.; Senker, J. (2002). "Dynamics of Anions and Cations in Hydrogensulfides of Alkali Metals (NaHS, KHS, RbHS): A Proton Nuclear Magnetic Resonance Study". Journal of Chemical Physics. 117 (3): 1269–1276. Bibcode:2002JChPh.117.1269H. doi:10.1063/1.1483860.
  3. Kurzer, F.; Lawson, A. (1962). "Thiobenzoylthioglycolic Acid". Organic Syntheses. 42: 100. doi:10.15227/orgsyn.042.0100.
  4. Robert L. Frank and James R. Blegen (1948). "Benzoyl Disulfide". Organic Syntheses. 28: 16. doi:10.15227/orgsyn.028.0016.
Potassium compounds
H, (pseudo)halogens
chalcogens
pnictogens
B, C group
transition metals
organic
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