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Isotopes of bismuth

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Isotopes of bismuth (83Bi)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
Bi synth 31.55 y β Pb
Bi synth 3.68×10 y β Pb
Bi 100% 2.01×10 y α Tl
Bi trace 5.012 d β Po
α Tl
Bi synth 3.04×10 y α Tl
Standard atomic weight Ar°(Bi)
  • 208.98040±0.00001
  • 208.98±0.01 (abridged)

Bismuth (83Bi) has 41 known isotopes, ranging from Bi to Bi. Bismuth has no stable isotopes, but does have one very long-lived isotope; thus, the standard atomic weight can be given as 208.98040(1). Although bismuth-209 is now known to be radioactive, it has classically been considered to be a stable isotope because it has a half-life of approximately 2.01×10 years, which is more than a billion times the age of the universe. Besides Bi, the most stable bismuth radioisotopes are Bi with a half-life of 3.04 million years, Bi with a half-life of 368,000 years and Bi, with a half-life of 32.9 years, none of which occurs in nature. All other isotopes have half-lives under 1 year, most under a day. Of naturally occurring radioisotopes, the most stable is radiogenic Bi with a half-life of 5.012 days. Bi is unusual for being a nuclear isomer with a half-life multiple orders of magnitude longer than that of the ground state.

List of isotopes


Nuclide
Historic
name
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Isotopic
abundance
Excitation energy
Bi 83 101 184.00135(13)# 6.6(15) ms α Tl 3+#
Bi 150(100)# keV 13(2) ms α Tl 10−#
Bi 83 102 184.99760(9)# 2.8+2.3
−1.0 μs
p (92%) Pb (1/2+)
α (8%) Tl
Bi 70(50)# keV 58(2) μs IT Bi (7/2−, 9/2−)
Bi 83 103 185.996623(18) 14.8(7) ms α (99.99%) Tl (3+)
β (?%) Pb
β, SF (0.011%) (various)
Bi 170(100)# keV 9.8(4) ms α (99.99%) Tl (10−)
β (?%) Pb
β, SF (0.011%) (various)
Bi 83 104 186.993147(11) 37(2) ms α Tl (9/2−)
Bi 108(8) keV 370(20) μs α Tl 1/2+
Bi 252(3) keV 7(5) μs IT Bi (13/2+)
Bi 83 105 187.992276(12) 60(3) ms α Tl (3+)
β, SF (0.0014%) (various)
Bi 66(30) keV >5 μs 7+#
Bi 153(30) keV 265(15) ms α Tl (10−)
β, SF (0.0046%) (various)
Bi 83 106 188.989195(22) 688(5) ms α Tl 9/2−
Bi 184(5) keV 5.0(1) ms α (83%) Tl 1/2+
IT (17%) Bi
Bi 357.6(5) keV 880(50) ns IT Bi 13/2+
Bi 83 107 189.988625(23) 6.3(1) s α (77%) Tl (3+)
β (23%) Pb
β, SF (6×10%) (various)
Bi 120(40) keV 6.2(1) s α (70%) Tl 10−
β (30%) Pb
β, SF (4×10%) (various)
Bi 121(15) keV 175(8) ns IT Bi (5−)
Bi 394(40) keV 1.3(8) μs IT Bi (8−)
Bi 83 108 190.985787(8) 12.4(3) s α (51%) Tl 9/2−
β (49%) Pb
Bi 242(4) keV 125(8) ms α (68%) Tl 1/2+
IT (?%) Bi
β (?%) Pb
Bi 429.7(5) keV 562(10) ns IT Bi 13/2+
Bi 1875(25)# keV 400(40) ns IT Bi 25/2-#
Bi 83 109 191.98547(3) 34.6(9) s β (88%) Pb (3+)
α (12%) Tl
Bi 140(30) keV 39.6(4) s β (90%) Pb 10−
α (10%) Tl
Bi 83 110 192.982947(8) 63.6(30) s β (96.5%) Pb 9/2−
α (3.5%) Tl
Bi 305(6) keV 3.20(14) s α (84%) Tl 1/2+
β (16%) Pb
Bi 605.53(18) keV 153(10) ns IT Bi 13/2+
Bi 2349.6(6) keV 85(3) μs IT Bi 29/2+
Bi 2405.1(7) keV 3.02(8) μs IT Bi (29/2−)
Bi 83 111 193.982799(6) 95(3) s β (99.54%) Pb 3+
α (0.46%) Tl
Bi 150(50) keV 125(2) s β Pb (6+, 7+)
Bi 163(4) keV 115(4) s β (99.80%) Pb (10−)
α (0.20%) Tl
Bi 83 112 194.980649(6) 183(4) s β (99.97%) Pb 9/2−
α (0.030%) Tl
Bi 399(6) keV 87(1) s β (67%) Pb 1/2+
α (33%) Tl
Bi 2381.0(5) keV 614(5) ns IT Bi (29/2−)
Bi 2615.9(5) keV 1.49(1) μs IT Bi 29/2+
Bi 83 113 195.980667(26) 5.13(20) min β Pb (3+)
α (0.00115%) Tl
Bi 166.4(29) keV 0.6(5) s IT Bi (7+)
Bi 272(3) keV 4.00(5) min β (74.2%) Pb (10−)
IT (25.8%) Bi
α (3.8×10%) Bi
Bi 83 114 196.978865(9) 9.33(50) min β Pb 9/2−
Bi 533(12) keV 5.04(16) min α (55%) Tl 1/2+
β (45%) Pb
Bi 2403(12) keV 263(13) ns IT Bi (29/2−)
Bi 2929.5(5) keV 209(30) ns IT Bi (31/2−)
Bi 83 115 197.979201(30) 10.3(3) min β Pb 3+
Bi 290(40) keV 11.6(3) min β Pb 7+
Bi 540(40) keV 7.7(5) s IT Bi 10−
Bi 83 116 198.977673(11) 27(1) min β Pb 9/2−
Bi 667(3) keV 24.70(15) min β (>98%) Pb (1/2+)
IT (<2%) Bi
α (0.01%) Tl
Bi 1962(23) keV 0.10(3) μs IT Bi 25/2+#
Bi 2548(23) keV 168(13) ns IT Bi 29/2−#
Bi 83 117 199.978131(24) 36.4(5) min β Pb 7+
Bi 100(70)# keV 31(2) min β (?%) Pb (2+)
IT (?%) Bi
Bi 428.20(10) keV 400(50) ms IT Bi (10−)
Bi 83 118 200.976995(13) 103(3) min β Pb 9/2−
Bi 846.35(18) keV 57.5(21) min β Pb 1/2+
α (?%) Tl
Bi 1973(23) keV 118(28) ns IT Bi 25/2+#
Bi 2012(23) keV 105(75) ns IT Bi 27/2+#
Bi 2781(23) keV 124(4) ns IT Bi 29/2−#
Bi 83 119 201.977723(15) 1.72(5) h β Pb 5+
α (<10%) Tl
Bi 625(12) keV 3.04(6) μs IT Bi 10−#
Bi 2617(12) keV 310(50) ns IT Bi (17+)
Bi 83 120 202.976892(14) 11.76(5) h β Pb 9/2−
Bi 1098.21(9) keV 305(5) ms IT Bi 1/2+
Bi 2041.5(6) keV 194(30) ns IT Bi 25/2+
Bi 83 121 203.977836(10) 11.22(10) h β Pb 6+
Bi 805.5(3) keV 13.0(1) ms IT Bi 10−
Bi 2833.4(11) keV 1.07(3) ms IT Bi 17+
Bi 83 122 204.977385(5) 14.91(7) d β Pb 9/2−
Bi 1497.17(9) keV 7.9(7) μs IT Bi 1/2+
Bi 2064.7(4) keV 100(6) ns IT Bi 21/2+
Bi 2139.0(7) keV 220(25) ns IT Bi 25/2+
Bi 83 123 205.978499(8) 6.243(3) d β Pb 6+
Bi 59.897(17) keV 7.7(2) μs IT Bi 4+
Bi 1044.8(7) keV 890(10) μs IT Bi 10−
Bi 9233.3(8) keV 155(15) ns IT Bi (28−)
Bi 10170.5(8) keV >2 μs IT Bi (31+)
Bi 83 124 206.9784706(26) 31.22(17) y β Pb 9/2−
Bi 2101.61(16) keV 182(6) μs IT Bi 21/2+
Bi 83 125 207.9797421(25) 3.68(4)×10 y β Pb 5+
Bi 1571.1(4) keV 2.58(4) ms IT Bi 10−
Bi
83 126 208.9803986(15) 2.01(8)×10 y
α Tl 9/2− 1.0000
Bi Radium E 83 127 209.9841202(15) 5.012(5) d β Po 1− Trace
α (1.32×10%) Tl
Bi 271.31(11) keV 3.04(6)×10 y α Tl 9−
Bi Actinium C 83 128 210.987269(6) 2.14(2) min α (99.72%) Tl 9/2− Trace
β (0.276%) Po
Bi 1257(10) keV 1.4(3) μs IT Bi (25/2−)
Bi Thorium C 83 129 211.991285(2) 60.55(6) min β (64.05%) Po 1− Trace
α (35.94%) Tl
β, α (0.014%) Pb
Bi 250(30) keV 25.0(2) min α (67%) Tl (8−, 9−)
β, α (30%) Pb
β (3%) Po
Bi 1479(30) keV 7.0(3) min β Po (18−)
Bi
83 130 212.994384(5) 45.60(4) min β (97.91%) Po 9/2− Trace
α (2.09%) Tl
Bi 1353(21) keV >168 s 25/2−#
Bi Radium C 83 131 213.998711(12) 19.9(4) min β (99.98%) Po 1− Trace
α (0.021%) Tl
β, α (0.003%) Pb
Bi 539(30) keV >93 s 8−#
Bi 83 132 215.001749(6) 7.62(13) min β Po (9/2−) Trace
Bi 1367(20)# keV 36.9(6) s IT (76.9%) Bi (25/2−)
β (23.1%) Po
Bi 83 133 216.006306(12) 2.21(4) min β Po (6−, 7−)
Bi 24(19) keV 6.6(21) min β Po 3−#
Bi 83 134 217.009372(19) 98.5(13) s β Po 9/2−#
Bi 1491(20) keV 3.0(2) μs IT Bi 25/2−#
Bi 83 135 218.014188(29) 33(1) s β Po 8−#
Bi 83 136 219.01752(22)# 8.7(29) s β Po 9/2−#
Bi 83 137 220.02250(32)# 9.5(57) s β Po 1−#
Bi 83 138 221.02598(32)# 2# s
9/2−#
Bi 83 139 222.03108(32)# 3# s
1−#
Bi 83 140 223.03461(43)# 1# s
9/2−#
Bi 83 141 224.03980(43)# 1# s
1−#
This table header & footer:
  1. Bi – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Bold half-life – nearly stable, half-life longer than age of universe.
  5. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition


    p: Proton emission
  6. Bold symbol as daughter – Daughter product is stable.
  7. ( ) spin value – Indicates spin with weak assignment arguments.
  8. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  9. ^ Order of ground state and isomer is uncertain.
  10. Formerly believed to be final decay product of 4n+1 decay chain
  11. Primordial radioisotope, also some is radiogenic from the extinct nuclide Np
  12. Formerly believed to be the heaviest stable nuclide
  13. ^ Intermediate decay product of U
  14. ^ Intermediate decay product of U
  15. Intermediate decay product of Th
  16. Used in medicine such as for cancer treatment.
  17. A byproduct of thorium reactors via U.
  18. Intermediate decay product of Np

Bismuth-213

Bismuth-213 (Bi) has a half-life of 45 minutes and decays via alpha emission. Commercially, bismuth-213 can be produced by bombarding radium with bremsstrahlung photons from a linear particle accelerator, which populates its progenitor actinium-225. In 1997, an antibody conjugate with Bi was used to treat patients with leukemia. This isotope has also been tried in targeted alpha therapy (TAT) program to treat a variety of cancers. Bismuth-213 is also found in the decay chain of uranium-233, which is the fuel bred by thorium reactors.

References

  1. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. "Standard Atomic Weights: Bismuth". CIAAW. 2005.
  3. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  4. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  5. Andreyev, A. N.; Ackermann, D.; Heßberger, F. P.; Hofmann, S.; Huyse, M.; Kojouharov, I.; Kindler, B.; Lommel, B.; Münzenberg, G.; Page, R. D.; Vel, K. Van de; Duppen, P. Van; Heyde, K. (1 October 2003). "α-decay spectroscopy of light odd-odd Bi isotopes - II: Bi and the new nuclide Bi" (PDF). The European Physical Journal A. 18 (1): 55–64. Bibcode:2003EPJA...18...55A. doi:10.1140/epja/i2003-10051-1. ISSN 1434-601X. S2CID 122369569. Retrieved 20 June 2023.
  6. Doherty, D. T.; Andreyev, A. N.; Seweryniak, D.; Woods, P. J.; Carpenter, M. P.; Auranen, K.; Ayangeakaa, A. D.; Back, B. B.; Bottoni, S.; Canete, L.; Cubiss, J. G.; Harker, J.; Haylett, T.; Huang, T.; Janssens, R. V. F.; Jenkins, D. G.; Kondev, F. G.; Lauritsen, T.; Lederer-Woods, C.; Li, J.; Müller-Gatermann, C.; Potterveld, D.; Reviol, W.; Savard, G.; Stolze, S.; Zhu, S. (12 November 2021). "Solving the Puzzles of the Decay of the Heaviest Known Proton-Emitting Nucleus Bi". Physical Review Letters. 127 (20): 202501. Bibcode:2021PhRvL.127t2501D. doi:10.1103/PhysRevLett.127.202501. hdl:20.500.11820/ac1e5604-7bba-4a25-a538-795ca4bdc875. ISSN 0031-9007. PMID 34860042. S2CID 244089059. Retrieved 20 June 2023.
  7. Imam, S (2001). "Advancements in cancer therapy with alpha-emitters: a review". International Journal of Radiation Oncology, Biology, Physics. 51 (1): 271–278. doi:10.1016/S0360-3016(01)01585-1. PMID 11516878.
Isotopes of the chemical elements
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