A chloride sulfite or sulfite chloride is a chemical compound that contains chloride and sulfite anions (SO3 Cl). The known compounds of this type are all late transition metal sulfito complexes. Chlorine may be present as a ligand (chloro) or as an ion (chloride). The sulfito ligand can connect to the metal atom by way of an oxygen, or a sulfur atom. It can also link to the metal atom using two oxygen atoms as a bidentate ligand.
Chloride sulfites are not to be confused with the chlorosulfites, which are compounds containing the SO2Cl ion or -SO2Cl group in organic compounds, where it is also called chlorosulfinate. The chlorosulfates also have the formula SO3Cl as a single ion, whereas chloride sulfites have three negative charges.
The mercury complex with formula ClHgSO3 is found in the acid gas scrubbers that purify pollution from smokestacks. However it decomposes and does not capture mercury in this application. This complex can form an ammonium salt: ammonium chlorosulfitomercurate(II) NH4, which decomposes over 130°C. The salt is formed from mercuric chloride and ammonium sulfite water solutions.
List
| name | formula | ratio
SO3:Cl |
mw | system | space group | unit cell | volume | density | optical | references |
|---|---|---|---|---|---|---|---|---|---|---|
| chlorosulfito bis-(1,2-diaminopropane)cobalt(III) monohydrate | Co(NH2CH2CH2CH2NH2)2(SO3)Cl·H2O | 1:1 | red brown | |||||||
| chlorosulfito bis-(1,2-diaminopropane)cobalt(III) tetrahydrate sodium chloride | Co(NH2CH2CH2CH2NH2)2(SO3)Cl·4H2O·NaCl | 1:1 | brown | |||||||
| chlorosulfito (1,2-diaminopropane)(ethylenediamine)cobalt(III) monohydrate sodium chloride | Co(NH2CH2CH2CH2NH2)(NH2CH2CH2NH2)(SO3)Cl·H2O·NaCl | 1:1 | brick red | |||||||
| chlorosulfito bis-(ethylenediamine)cobalt(III) monohydrate | ·H2O | 1:1 | pink brown | |||||||
| ammino sulfito bis-(ethylenediamine)cobalt(III) chloride | Cl | yellow brown | ||||||||
| sulfito bis-(ethylenediamine)cobalt(III) chloride | Cl | brown-red | ||||||||
| sulfito tetraammino chloro osmium | OsSO3(NH3)4Cl | 1:1 | pink brown | |||||||
| Na6·10H2O | 4:2 | purple | ||||||||
| Na7·6H2O | 5:1 | pale violet | ||||||||
| K8 | 4:4 | brown | ||||||||
| sulfito aquo octaammino μ-nitrido diosmium trichloride | Cl3 | 1:3 | yellow brown | |||||||
| Na2 | 2:1 | |||||||||
| trisodium diaquadichlorodisulfitoiridate(III) heptahydrate | Na3·7H2O | Pnma | Z=4 | yellow | ||||||
| trisodium disulfito dichloro diammino iridium tetrahydrate | Na3·4H2O | 2:2 | ||||||||
| trisodium disulfito dichloro diammino iridium hexahydrate | Na3·6H2O | 2:2 | pale yellow | |||||||
| tripotassium diaquadichlorodisulfitoiridate(III) dihydrate | K3·2H2O | C2 | Z=2 | yellow | ||||||
| Na5 | 2:4 | |||||||||
| pentapotassium disulfito tetrachloro iridium hexahydrate | K5·6H2O | light orange | ||||||||
| pentasodium dichlorobis(hydrogendisulfito)iridate(III) | trans-Na5·10H2O | C2/c | pale yellow | |||||||
| pentapotassium dichlorobis(hydrogendisulfito)iridates(III) | trans-K5·5H2O | pale yellow | ||||||||
| Na7 | 4:2 | |||||||||
| hepta sodium tetrasulfito dichloro iridium heptahydrate | Na7·7H2O | pale yellow | ||||||||
| K7 | 4:2 | |||||||||
| (NH4)5lr(SO3)2Cl4 | 2:4 | monoclinic | P21/n | a = 11.10 b = 7.25 c = 7.25 β= 96.5 Z = 2 | ||||||
| (NH4)4lr(SO3)2Cl3·4H2O | 2:3 | monoclinic | a = 10.44 b = 9.46 c = 7.48 β = 90.5, Z = 2 | |||||||
| NH4 | 1:1 | Pnma | a=15.430 b=5.525 c=6.679 Z=4 | |||||||
| K·KCl·H2O | 1:2 | 761.18 | triclinc | P1_ | a = 6.1571 b = 7.1342 c = 10.649 α = 76.889, β = 88.364, γ = 69.758° Z=4 | 426.8 | 4.358 | |||
| K·KCl·HgCl2 | 1:4 | 701.24 | monoclinic | P21/m | a=9.532 b=5.9593 c=10.176 β =110.522 Z=2 | 541.3 | 4.302 | |||
| K·HgCl2 | 1:3 | 626.69 | orthorhombic | Cmc21 | a=5.9313 b=21.746 c=6.7899 Z=4 | 879.79 | 4.753 | |||
| NH4·HgCl2 | 1:3 | 605.65 | orthorhombic | Cmc21 | a=5.962 b=22.247 c=6.958 Z=4 | 923.0 | 4.358 | |||
| NH4·HgCl2·NH4Cl | 1:4 | 659.12 | monoclinic | P21/m | a=9.712 b=6.138 c=10.401 β =110.92 Z=2 | 579.2 | 3.779 | |||
| (K)2·KCl·HgCl2 | 2:5 | 1056.44 | orthorhombic | Pnma | a=22.158 b=5.9736 c=12.249 Z=4 | 1621.2 | 4.328 |
References
- Senior, Constance (October 2007). "Review of the Role of Aqueous Chemistry in Mercury Removal by Acid Gas Scrubbers on Incinerator Systems". Environmental Engineering Science. 24 (8): 1129–1134. doi:10.1089/ees.2007.0105.
- ^ Weil, Matthias; Breitinger, Dietrich K.; Liehr, Günther; Zürbig, Jürgen (March 2007). "Structural Investigations and Thermal Behaviour of Mercury(II) Sulfito Complexes". Zeitschrift für anorganische und allgemeine Chemie. 633 (3): 429–434. doi:10.1002/zaac.200600313.
- ^ Salib, Kamal A. R.; Abu El-Wafa, Samy M.; El-Maraghy, Salah B.; El-Sayed, Saied M. (December 1989). "Sulfitoamine Complexes of Cobalt(III)". Phosphorus, Sulfur, and Silicon and the Related Elements. 46 (3–4): 131–138. doi:10.1080/10426508909412058. ISSN 1042-6507.
- ^ Baldwin, M. E. (1961). "599. Sulphitobis(ethylenediamine)cobalt(III) complexes". Journal of the Chemical Society (Resumed): 3123–3128. doi:10.1039/jr9610003123. ISSN 0368-1769.
- ^ Hall, J.P.; Griffith, W.P. (January 1981). "Vibrational spectra of group VIII sulphito complexes". Inorganica Chimica Acta. 48: 65–71. doi:10.1016/S0020-1693(00)90068-9.
- ^ Livingstone, Stanley E. (2017-01-31). The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum: Pergamon Texts in Inorganic Chemistry, Volume 25. Elsevier. p. 1229. ISBN 978-1-4831-5840-2.
- ^ Livingstone, Stanley E. (2017). The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum: Pergamon Texts in Inorganic Chemistry, Volume 25. Elsevier. p. 1265. ISBN 978-1-4831-5840-2.
- Ferrari, A., and C. Colla. "Iridionitrites of ammonium, potassium, rubidium, cæsium and thallium." Gazzetta Chimica Italiana 63 (1933): 507-513
- ^ Breitinger, D.K; Bogner, A (May 1999). "Vibrational spectra of sulfito and hydrogensulfito complexes of iridium". Journal of Molecular Structure. 482–483 (1–3): 125–129. Bibcode:1999JMoSt.482..125B. doi:10.1016/S0022-2860(98)00635-8.
- russ j inor chem 6 1961 1247
- ^ Porai-Koshits, M. A.; Ionov, S. P.; Novozhenyuk, Z. M. (1965). "Crystal structure of some trivalent iridium compounds containing sulfite groups in the complex ion". Journal of Structural Chemistry. 6 (1): 161–162. doi:10.1007/BF00743893. ISSN 0022-4766. S2CID 98609854.
- ^ Weil, Matthias; Baumann, Stefan; Breitinger, Dietrich K. (August 2008). "Structural Studies of New Sulfito Mercurates(II) with General Formula xM middot; y Hg X 2 · zM X· n H 2 O ( M = NH 4 , K; X = Cl, Br)". Zeitschrift für anorganische und allgemeine Chemie. 634 (10): 1742–1748. doi:10.1002/zaac.200800159.
| Compounds containing the sulfite group (SO2−3) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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