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Isotopes of chromium

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Isotopes of chromium (24Cr)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
Cr 4.34% stable
Cr synth 27.7025 d ε V
γ
Cr 83.8% stable
Cr 9.50% stable
Cr 2.37% stable
Standard atomic weight Ar°(Cr)
  • 51.9961±0.0006
  • 51.996±0.001 (abridged)

Naturally occurring chromium (24Cr) is composed of four stable isotopes; Cr, Cr, Cr, and Cr with Cr being the most abundant (83.789% natural abundance). Cr is suspected of decaying by ββ to Ti with a half-life of (more than) 1.8×10 years. Twenty-two radioisotopes, all of which are entirely synthetic, have been characterized, the most stable being Cr with a half-life of 27.7 days. All of the remaining radioactive isotopes have half-lives that are less than 24 hours and the majority of these have half-lives that are less than 1 minute. This element also has two meta states, Cr, the more stable one, and Cr, the least stable isotope or isomer.

Cr is the radiogenic decay product of Mn. Chromium isotopic contents are typically combined with manganese isotopic contents and have found application in isotope geology. Mn-Cr isotope ratios reinforce the evidence from Al and Pd for the early history of the Solar System. Variations in Cr/Cr and Mn/Cr ratios from several meteorites indicate an initial Mn/Mn ratio that suggests Mn-Cr isotope systematics must result from in-situ decay of Mn in differentiated planetary bodies. Hence Cr provides additional evidence for nucleosynthetic processes immediately before coalescence of the Solar System. The same isotope is preferentially involved in certain leaching reactions, thereby allowing its abundance in seawater sediments to be used as a proxy for atmospheric oxygen concentrations.

The isotopes of chromium range from Cr to Cr. The primary decay mode before the most abundant stable isotope, Cr, is electron capture and the primary mode after is beta decay.

List of isotopes


Nuclide
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Natural abundance (mole fraction)
Excitation energy Normal proportion Range of variation
Cr 24 18 42.00758(32)# 13.3(10) ms β (94.4%) V 0+
β, p (5.6%) Ti
Cr 24 19 42.99789(22)# 21.1(3) ms β, p (79.3%) Ti (3/2+)
β, 2p (11.6%) Sc
β (8.97%) V
β, 3p (0.13%) Ca
Cr 24 20 43.985591(55) 42.8(6) ms β (88%) V 0+
β, p (12%) Ti
Cr 24 21 44.979050(38) 60.9(4) ms β (65.6%) V 7/2−#
β, p (34.4%) Ti
Cr 107(1) keV >80 μs IT Cr (3/2)
Cr 24 22 45.968361(12) 224.3(13) ms β V 0+
Cr 24 23 46.9628950(56) 461.6(15) ms β V 3/2−
Cr 24 24 47.9540294(78) 21.56(3) h β V 0+
Cr 24 25 48.9513337(24) 42.3(1) min β V 5/2−
Cr 24 26 49.94604221(10) Observationally Stable 0+ 0.04345(13)
Cr 24 27 50.94476539(18) 27.7015(11) d EC V 7/2−
Cr 24 28 51.94050471(12) Stable 0+ 0.83789(18)
Cr 24 29 52.94064630(12) Stable 3/2− 0.09501(17)
Cr 24 30 53.93887736(14) Stable 0+ 0.02365(7)
Cr 24 31 54.94083664(25) 3.497(3) min β Mn 3/2−
Cr 24 32 55.94064898(62) 5.94(10) min β Mn 0+
Cr 24 33 56.9436121(20) 21.1(10) s β Mn (3/2)−
Cr 24 34 57.9441845(32) 7.0(3) s β Mn 0+
Cr 24 35 58.94834543(72) 1.05(9) s β Mn (1/2−)
Cr 502.7(11) keV 96(20) μs IT Cr (9/2+)
Cr 24 36 59.9496417(12) 490(10) ms β Mn 0+
Cr 24 37 60.9543781(20) 243(9) ms β Mn (5/2−)
Cr 24 38 61.9561429(37) 206(12) ms β Mn 0+
Cr 24 39 62.961161(78) 129(2) ms β Mn 1/2−#
Cr 24 40 63.96389(32) 43(1) ms β Mn 0+
Cr 24 41 64.96961(22)# 27.5(21) ms β Mn 1/2−#
Cr 24 42 65.97301(32)# 23.8(18) ms β Mn 0+
Cr 24 43 66.97931(43)# 11# ms
1/2−#
Cr 24 44 67.98316(54)# 10# ms
0+
Cr 24 45 68.98966(54)# 6# ms
7/2+#
Cr 24 46 69.99395(64)# 6# ms
0+
This table header & footer:
  1. Cr – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition


    p: Proton emission
  6. Bold symbol as daughter – Daughter product is stable.
  7. ( ) spin value – Indicates spin with weak assignment arguments.
  8. Order of ground state and isomer is uncertain.
  9. Suspected of decaying by double β decay to Ti with a half-life of no less than 1.3×10 years

Chromium-51

Chromium-51 is a synthetic radioactive isotope of chromium having a half-life of 27.7 days and decaying by electron capture with emission of gamma rays (0.32 MeV); it is used to label red blood cells for measurement of mass or volume, survival time, and sequestration studies, for the diagnosis of gastrointestinal bleeding, and to label platelets to study their survival. It has a role as a radioactive label. Chromium Cr-51 has been used as a radioactive label for decades. It is used as a diagnostic radiopharmaceutical agent in nephrology to determine glomerular filtration rate, and in hematology to determine red blood cell volume or mass, study the red blood cell survival time and evaluate blood loss.

External links

References

  1. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. "Standard Atomic Weights: Chromium". CIAAW. 1983.
  3. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  4. R. Frei; C. Gaucher; S. W. Poulton; D. E. Canfield (2009). "Fluctuations in Precambrian atmospheric oxygenation recorded by chromium isotopes". Nature. 461 (7261): 250–3. Bibcode:2009Natur.461..250F. doi:10.1038/nature08266. PMID 19741707. S2CID 4373201.
  5. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  6. "Chromium-51".
Isotopes of the chemical elements
Group 1 2   3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Period Hydrogen and
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Alkaline
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