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Ethyldichloroarsine

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Ethyldichloroarsine
Names
Preferred IUPAC name Ethylarsonous dichloride
Other names ED
Dichloroethylarsane; DICK
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.009.019 Edit this at Wikidata
EC Number
  • 209-919-3
PubChem CID
RTECS number
  • CH3500000
UNII
UN number 1892
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C2H5AsCl2/c1-2-3(4)5/h2H2,1H3Key: LQSFEOMOHFPNEB-UHFFFAOYSA-N
SMILES
  • CC(Cl)Cl
Properties
Chemical formula C2H5AsCl2
Molar mass 174.8893 g/mol
Appearance Colorless, mobile liquid
Density 1.742 @ 14 °C
Melting point −65 °C (−85 °F; 208 K)
Boiling point 156 °C (313 °F; 429 K) (decomposes)
Solubility in water Soluble in alcohol, benzene, ether, and water
Hazards
Occupational safety and health (OHS/OSH):
Main hazards Highly toxic, irritant
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Ethyldichloroarsine, sometimes abbreviated as "ED" and "CY" and also known as ethyl Dick, is an organoarsenic compound with the formula CH3CH2AsCl2. This colourless volatile liquid is a highly toxic obsolete vesicant or blister agent that was used during World War I in chemical warfare. The molecule is pyramidal with the Cl-As-Cl and C-As-Cl angles approaching 90° (see image). Ethyldichloroarsine has high chronic toxicity, similar to lewisite.

References

  1. Wood JR (May 1944). "Chemical Warfare-A Chemical and Toxicological Review". American Journal of Public Health and the Nation's Health. 34 (5): 455–60. doi:10.2105/AJPH.34.5.455. PMC 1625133. PMID 18015982.
  2. "Methyldichloroarsine". NorthShore University HealthSystem. Archived from the original on March 7, 2011.
  3. Okumura A, Takada Y, Watanabe S, Hashimoto H, Ezawa N, Seto Y, et al. (July 2016). "In-Line Reactions and Ionizations of Vaporized Diphenylchloroarsine and Diphenylcyanoarsine in Atmospheric Pressure Chemical Ionization Mass Spectrometry". Journal of the American Society for Mass Spectrometry. 27 (7): 1219–26. Bibcode:2016JASMS..27.1219O. doi:10.1007/s13361-016-1394-0. PMID 27098411.
Blood agents
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  • Ethyldichloroarsine (ED)
  • Methyldichloroarsine (MD)
  • Phenyldichloroarsine (PD)
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