Misplaced Pages

Gadolinium(III) nitrate

Article snapshot taken from Wikipedia with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
(Redirected from Gadolinium nitrate)
Gadolinium(III) nitrate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.385 Edit this at Wikidata
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/Gd.3NO3/c;3*2-1(3)4/q+3;3*-1Key: MWFSXYMZCVAQCC-UHFFFAOYSA-N
  • InChI=1/Gd.3NO3/c;3*2-1(3)4/q+3;3*-1Key: MWFSXYMZCVAQCC-UHFFFAOYAX
SMILES
  • .O=().()=O.()=O
Properties
Chemical formula Gd(NO3)3
Molar mass 343.26 g/mol
Appearance White crystalline solid
Density 2.3 g/cm
Melting point 91 °C (196 °F; 364 K)
Solubility in water Soluble
Hazards
Safety data sheet (SDS) External MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Gadolinium(III) nitrate is an inorganic compound of gadolinium. This salt is used as a water-soluble neutron poison in nuclear reactors. Gadolinium nitrate, like all nitrate salts, is an oxidizing agent.

The most common form of this substance is hexahydrate Gd(NO3)3•6H2O with molecular weight 451.36 g/mol and CAS Number: 19598-90-4.

Use

Gadolinium nitrate was used at the Savannah River Site heavy water nuclear reactors and had to be separated from the heavy water for storage or reuse. The Canadian CANDU reactor, a pressurized heavy water reactor, also uses gadolinium nitrate as a water-soluble neutron poison in heavy water.

Gadolinium nitrate is also used as a raw material in the production of other gadolinium compounds, for production of specialty glasses and ceramics and as a phosphor.

References

  1. DOE Fundamentals Handbook: Nuclear Physics and Reactor Theory (PDF). U.S. Department of Energy. January 1993. p. 31. Archived from the original (PDF) on 2008-04-23. Retrieved 2007-09-26.
  2. E. Wilde; C. Berry. "Novel Method for Removing Gadolinium from Used Heavy Water Reactor Moderator".
  3. E.W. Wilde; M.B. Goli; C.J. Berry; J.W. Santo Domingo; H.L. Martin. "Novel Method for Removing Gadolinium from Used Heavy Water Reactor Moderator" (PDF).
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)−4 RONO2
+CO3
+C2O4
NO3
NH4NO3
HOONO2 FNO3
+F
Ne
NaNO3 Mg(NO3)2 Al(NO3)3
Al(NO3)−4
Si P +SO4 ClONO2
+Cl
Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)2
Fe(NO3)3
Co(NO3)2
Co(NO3)3
Ni(NO3)2 CuNO3
Cu(NO3)2
Zn(NO3)2 Ga(NO3)3 Ge As +SeO3 BrNO3
+Br
Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 NbO(NO3)3 MoO2(NO3)2 Tc Ru Rh(NO3)3 Pd(NO3)2 AgNO3 Cd(NO3)2 In(NO3)3 Sn(NO3)4 Sb4O4(OH)2(NO3)2 Te INO3
+IO3
Xe(NO3)2
CsNO3 Ba(NO3)2 * Lu(NO3)3 Hf(NO3)4 TaO(NO3)3 WO2(NO3)2 ReO3NO3 Os Ir3O(NO3)10 Pt Au(NO3)−4 Hg2(NO3)2
Hg(NO3)2
TlNO3
Tl(NO3)3
Pb(NO3)2 Bi(NO3)3
BiO(NO3)
Po(NO3)4 At Rn
FrNO3 Ra(NO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(NO3)3 Ce(NO3)3
Ce(NO3)4
Pr(NO3)3 Nd(NO3)3 Pm(NO3)3 Sm(NO3)3 Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy(NO3)3 Ho(NO3)3 Er(NO3)3 Tm(NO3)3 Yb(NO3)3
** Ac(NO3)3 Th(NO3)4 PaO(NO3)3 UO2(NO3)2 Np(NO3)4 Pu(NO3)4 Am(NO3)3 Cm(NO3)3 Bk(NO3)3 Cf(NO3)3 Es Fm Md No
Gadolinium compounds
Gadolinium(III)
Organogadolinium(III)
  • Gd(C5H7O2)3
  • Categories: