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The EO6, between Larissa and the interchange with the A3 motorway near Trikala, is being upgraded to dual carriageway with expressway characteristics. Meanwhile, the A1 motorway provides a faster route than the overlapping EO1/EO6 section between Velestino and Larissa, and the A2 motorway (Egnatia Odos) does the same between Malakasi and Igoumenitsa.
This article contains a bulleted list or table of intersections which should be presented in a properly formatted junction table. Please consult this guideline for information on how to create one. Please improve this article if you can. (November 2021)
Ministerial Decision G25871 of 9 July 1963 created the current EO6 from all or part of three short-lived national roads (listed from east to west), which existed by royal decree from 1955 to 1963: the old EO14 from Volos to Larissa; the old EO23 from Larissa to Ioannina; and the old EO26 from Ioannina to Igoumenitsa. Until 1975, the EO6 formed part of the old European route E87 from Volos to Ioannina.
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