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Standard atomic weight Ar°(Nd) | ||||||||||||||||||||||||||||||||||||||||||||||
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Naturally occurring neodymium (60Nd) is composed of five stable isotopes, Nd, Nd, Nd, Nd and Nd, with Nd being the most abundant (27.2% natural abundance), and two long-lived radioisotopes, Nd and Nd. In all, 35 radioisotopes of neodymium have been characterized up to now, with the most stable being naturally occurring isotopes Nd (alpha decay, a half-life (t1/2) of 2.29×10 years) and Nd (double beta decay, t1/2 of 9.3×10 years), and for practical purposes they can be considered to be stable as well. All of the remaining radioactive isotopes have half-lives that are less than 12 days, and the majority of these have half-lives that are less than 70 seconds; the most stable artificial isotope is Nd with a half-life of 10.98 days. This element also has 15 known meta states with the most stable being Nd (t1/2 5.5 hours), Nd (t1/2 5.5 minutes) and Nd (t1/2 ~70 seconds).
The primary decay modes for isotopes lighter than the most abundant stable isotope (also the only theoretically stable isotope), Nd, are electron capture and positron decay, and the primary mode for heavier radioisotopes is beta decay. The primary decay products for lighter radioisotopes are praseodymium isotopes and the primary products for heavier ones are promethium isotopes.
Neodymium isotopes as fission products
Neodymium is one of the more common fission products that results from the splitting of uranium-233, uranium-235, plutonium-239 and plutonium-241. The distribution of resulting neodymium isotopes is distinctly different than those found in crustal rock formation on Earth. One of the methods used to verify that the Oklo Fossil Reactors in Gabon had produced a natural nuclear fission reactor some two billion years before present was to compare the relative abundances of neodymium isotopes found at the reactor site with those found elsewhere on Earth.
List of isotopes
Nuclide |
Z | N | Isotopic mass (Da) |
Half-life |
Decay mode |
Daughter isotope |
Spin and parity |
Natural abundance (mole fraction) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Excitation energy | Normal proportion | Range of variation | |||||||||||||||||
Nd | 60 | 64 | 123.95223(64)# | 500# ms | 0+ | ||||||||||||||
Nd | 60 | 65 | 124.94888(43)# | 600(150) ms | 5/2(+#) | ||||||||||||||
Nd | 60 | 66 | 125.94322(43)# | 1# s | β | Pr | 0+ | ||||||||||||
Nd | 60 | 67 | 126.94050(43)# | 1.8(4) s | β | Pr | 5/2+# | ||||||||||||
β, p (rare) | Ce | ||||||||||||||||||
Nd | 60 | 68 | 127.93539(21)# | 5# s | β | Pr | 0+ | ||||||||||||
β, p (rare) | Ce | ||||||||||||||||||
Nd | 60 | 69 | 128.93319(22)# | 4.9(2) s | β | Pr | 5/2+# | ||||||||||||
β, p (rare) | Ce | ||||||||||||||||||
Nd | 60 | 70 | 129.92851(3) | 21(3) s | β | Pr | 0+ | ||||||||||||
Nd | 60 | 71 | 130.92725(3) | 33(3) s | β | Pr | (5/2)(+#) | ||||||||||||
β, p (rare) | Ce | ||||||||||||||||||
Nd | 60 | 72 | 131.923321(26) | 1.56(10) min | β | Pr | 0+ | ||||||||||||
Nd | 60 | 73 | 132.92235(5) | 70(10) s | β | Pr | (7/2+) | ||||||||||||
Nd | 127.97(11) keV | ~70 s | β | Pr | (1/2)+ | ||||||||||||||
Nd | 176.10(10) keV | ~300 ns | (9/2–) | ||||||||||||||||
Nd | 60 | 74 | 133.918790(13) | 8.5(15) min | β | Pr | 0+ | ||||||||||||
Nd | 2293.1(4) keV | 410(30) μs | (8)– | ||||||||||||||||
Nd | 60 | 75 | 134.918181(21) | 12.4(6) min | β | Pr | 9/2(–) | ||||||||||||
Nd | 65.0(2) keV | 5.5(5) min | β | Pr | (1/2+) | ||||||||||||||
Nd | 60 | 76 | 135.914976(13) | 50.65(33) min | β | Pr | 0+ | ||||||||||||
Nd | 60 | 77 | 136.914567(12) | 38.5(15) min | β | Pr | 1/2+ | ||||||||||||
Nd | 519.43(17) keV | 1.60(15) s | IT | Nd | (11/2–) | ||||||||||||||
Nd | 60 | 78 | 137.911950(13) | 5.04(9) h | β | Pr | 0+ | ||||||||||||
Nd | 3174.9(4) keV | 410(50) ns | (10+) | ||||||||||||||||
Nd | 60 | 79 | 138.911978(28) | 29.7(5) min | β | Pr | 3/2+ | ||||||||||||
Nd | 231.15(5) keV | 5.50(20) h | β (88.2%) | Pr | 11/2– | ||||||||||||||
IT (11.8%) | Nd | ||||||||||||||||||
Nd | 2570.9+X keV | ≥141 ns | |||||||||||||||||
Nd | 60 | 80 | 139.90955(3) | 3.37(2) d | EC | Pr | 0+ | ||||||||||||
Nd | 2221.4(1) keV | 600(50) μs | 7– | ||||||||||||||||
Nd | 60 | 81 | 140.909610(4) | 2.49(3) h | β | Pr | 3/2+ | ||||||||||||
Nd | 756.51(5) keV | 62.0(8) s | IT (99.95%) | Nd | 11/2– | ||||||||||||||
β (.05%) | Pr | ||||||||||||||||||
Nd | 60 | 82 | 141.9077233(25) | Stable | 0+ | 0.272(5) | 0.2680–0.2730 | ||||||||||||
Nd | 60 | 83 | 142.9098143(25) | Observationally Stable | 7/2− | 0.122(2) | 0.1212–0.1232 | ||||||||||||
Nd | 60 | 84 | 143.9100873(25) | 2.29(16)×10 y | α | Ce | 0+ | 0.238(3) | 0.2379–0.2397 | ||||||||||
Nd | 60 | 85 | 144.9125736(25) | Observationally Stable | 7/2− | 0.083(1) | 0.0823–0.0835 | ||||||||||||
Nd | 60 | 86 | 145.9131169(25) | Observationally Stable | 0+ | 0.172(3) | 0.1706–0.1735 | ||||||||||||
Nd | 60 | 87 | 146.9161004(25) | 10.98(1) d | β | Pm | 5/2− | ||||||||||||
Nd | 60 | 88 | 147.916893(3) | Observationally Stable | 0+ | 0.057(1) | 0.0566–0.0578 | ||||||||||||
Nd | 60 | 89 | 148.920149(3) | 1.728(1) h | β | Pm | 5/2− | ||||||||||||
Nd | 60 | 90 | 149.920891(3) | 9.3(7)×10 y | ββ | Sm | 0+ | 0.056(2) | 0.0553–0.0569 | ||||||||||
Nd | 60 | 91 | 150.923829(3) | 12.44(7) min | β | Pm | 3/2+ | ||||||||||||
Nd | 60 | 92 | 151.924682(26) | 11.4(2) min | β | Pm | 0+ | ||||||||||||
Nd | 60 | 93 | 152.927698(29) | 31.6(10) s | β | Pm | (3/2)− | ||||||||||||
Nd | 60 | 94 | 153.92948(12) | 25.9(2) s | β | Pm | 0+ | ||||||||||||
Nd | 480(150)# keV | 1.3(5) μs | |||||||||||||||||
Nd | 1349(10) keV | >1 μs | (5−) | ||||||||||||||||
Nd | 60 | 95 | 154.93293(16)# | 8.9(2) s | β | Pm | 3/2−# | ||||||||||||
Nd | 60 | 96 | 155.93502(22) | 5.49(7) s | β | Pm | 0+ | ||||||||||||
Nd | 1432(5) keV | 135 ns | 5− | ||||||||||||||||
Nd | 60 | 97 | 156.93903(21)# | 1.17(4) s | β | Pm | 5/2−# | ||||||||||||
Nd | 60 | 98 | 157.94160(43)# | 810(30) ms | β | Pm | 0+ | ||||||||||||
Nd | 1648.1(14) keV | 339(20) ns | IT | Nd | (6−) | ||||||||||||||
Nd | 60 | 99 | 158.94609(54)# | 500(30) ms | β | Pm | 7/2+# | ||||||||||||
Nd | 60 | 100 | 159.94909(64)# | 439(37) ms | β | Pm | 0+ | ||||||||||||
Nd | 1107.9(9) keV | 1.63(21) μs | IT | Nd | (4−) | ||||||||||||||
Nd | 60 | 101 | 160.95388(75)# | 215(76) ms | β | Pm | 1/2−# | ||||||||||||
Nd | 60 | 102 | 310(200) ms | β | Pm | 0+ | |||||||||||||
Nd | 60 | 103 | 80# ms | β | Pm | 5/2−# | |||||||||||||
This table header & footer: |
- Nd – Excited nuclear isomer.
- ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- Bold half-life – nearly stable, half-life longer than age of universe.
- ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
-
Modes of decay:
EC: Electron capture IT: Isomeric transition
p: Proton emission - Bold symbol as daughter – Daughter product is stable.
- ( ) spin value – Indicates spin with weak assignment arguments.
- ^ Fission product
- Believed to undergo α decay to Ce with a half-life over 2.8×10 years
- ^ Primordial radionuclide
- Believed to undergo α decay to Ce with a half-life of over 6.1×10 years
- Believed to undergo ββ decay to Sm or α decay to Ce with a half-life of over 3.3×10 years
- Believed to undergo ββ decay to Sm or α decay to Ce with a half-life of over 1.2×10 years
- Predicted to be capable of undergoing triple beta decay and quadruple beta decay with very long partial half-lives
References
- ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- "Standard Atomic Weights: Neodymium". CIAAW. 2005.
- Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
- Hemond, C.; Menet, C.; Menager, M.T. (1991). "U and Nd Isotopes from the New Oklo Reactor 10 (GABON): Evidence for Radioelements Migration". MRS Proceedings. 257. doi:10.1557/PROC-257-489.
- "Oklo's Natural Nuclear Reactors". 24 October 2020.
- "The Implications of the Oklo Phenomenon on the Constancy of Radiometric Decay Rates".
- ^ Sokur, N.V.; Belli, P.; Bernabei, R.; Boiko, R.S.; Cappella, F.; Caracciolo, V.; Cerulli, R.; Danevich, F.A.; Incicchitti, A.; Kasperovych, D.V.; Kobychev, V.V.; Laubenstein, M.; Leoncini, A.; Merlo, V.; Polischuk, O.G.; Tretyak, V.I. (11 July 2023). Alpha decay of naturally occurring neodymium isotopes. XII International Conference on New Frontiers in Physics.
- ^ Belli, P.; Bernabei, R.; Danevich, F. A.; Incicchitti, A.; Tretyak, V. I. (2019). "Experimental searches for rare alpha and beta decays". European Physical Journal A. 55 (140): 4–6. arXiv:1908.11458. Bibcode:2019EPJA...55..140B. doi:10.1140/epja/i2019-12823-2. S2CID 201664098.
- Hartley, D. J.; Kondev, F. G.; Carpenter, M. P.; Clark, J. A.; Copp, P.; Kay, B.; Lauritsen, T.; Savard, G.; Seweryniak, D.; Wilson, G. L.; Wu, J. (2023-08-14). "First β-decay spectroscopy study of Nd". Physical Review C. 108 (2). American Physical Society (APS): 024307. Bibcode:2023PhRvC.108b4307H. doi:10.1103/physrevc.108.024307. ISSN 2469-9985. S2CID 260913513.
- Isotope masses from:
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- Isotopic compositions and standard atomic masses from:
- de Laeter, John Robert; Böhlke, John Karl; De Bièvre, Paul; Hidaka, Hiroshi; Peiser, H. Steffen; Rosman, Kevin J. R.; Taylor, Philip D. P. (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- Wieser, Michael E. (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051.
- "News & Notices: Standard Atomic Weights Revised". International Union of Pure and Applied Chemistry. 19 October 2005.
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.