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Isotopes of radium

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Isotopes of radium (88Ra)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
Ra trace 11.43 d α Rn
Ra trace 3.6319 d α Rn
Ra trace 14.9 d β Ac
α Rn
Ra trace 1599 y α Rn
Ra trace 5.75 y β Ac

Radium (88Ra) has no stable or nearly stable isotopes, and thus a standard atomic weight cannot be given. The longest lived, and most common, isotope of radium is Ra with a half-life of 1600 years. Ra occurs in the decay chain of U (often referred to as the radium series). Radium has 34 known isotopes from Ra to Ra.

In the early history of the study of radioactivity, the different natural isotopes of radium were given different names, as it was not until Frederick Soddy's scientific career in the early 1900s that the concept of isotopes was realized. In this scheme, Ra was named actinium X (AcX), Ra thorium X (ThX), Ra radium (Ra), and Ra mesothorium 1 (MsTh1). When it was realized that all of these are isotopes of the same element, many of these names fell out of use, and "radium" came to refer to all isotopes, not just Ra, though mesothorium 1 in particular was still used for some time, with a footnote explaining that it referred to Ra. Some of radium-226's decay products received historical names including "radium", ranging from radium A to radium G, with the letter indicating approximately how far they were down the chain from their parent Ra.

In 2013 it was discovered that the nucleus of radium-224 is pear-shaped. This was the first discovery of an asymmetrical nucleus.

List of isotopes


Nuclide
Historic
name
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Isotopic
abundance
Excitation energy
Ra 88 113 8+40
−4 ms
α Rn (3/2−)
Ra 260(30) keV 1.6+7.7
−0.7 ms
α Rn (13/2+)
Ra 88 114 202.00989(7) 3.8+1.3
−0.8 ms
α Rn 0+
Ra 88 115 203.00927(9) 4(3) ms α Rn (3/2−)
β (rare) Fr
Ra 220(90) keV 41(17) ms α Rn (13/2+)
β (rare) Fr
Ra 88 116 204.006500(17) 60(11) ms
α (99.7%) Rn 0+
β (.3%) Fr
Ra 88 117 205.00627(9) 220(40) ms
α Rn (3/2−)
β (rare) Fr
Ra 310(110)# keV 180(50) ms
α Rn (13/2+)
IT (rare) Ra
Ra 88 118 206.003827(19) 0.24(2) s α Rn 0+
Ra 88 119 207.00380(6) 1.3(2) s α (90%) Rn (5/2−, 3/2−)
β (10%) Fr
Ra 560(50) keV 57(8) ms IT (85%) Ra (13/2+)
α (15%) Rn
β (.55%) Fr
Ra 88 120 208.001840(17) 1.3(2) s α (95%) Rn 0+
β (5%) Fr
Ra 1800(200) keV 270 ns (8+)
Ra 88 121 209.00199(5) 4.6(2) s α (90%) Rn 5/2−
β (10%) Fr
Ra 88 122 210.000495(16) 3.7(2) s α (96%) Rn 0+
β (4%) Fr
Ra 1800(200) keV 2.24 μs (8+)
Ra 88 123 211.000898(28) 13(2) s α (97%) Rn 5/2(−)
β (3%) Fr
Ra 88 124 211.999794(12) 13.0(2) s α (85%) Rn 0+
β (15%) Fr
Ra 1958.4(5) keV 10.9(4) μs (8)+
Ra 2613.4(5) keV 0.85(13) μs (11)−
Ra 88 125 213.000384(22) 2.74(6) min α (80%) Rn 1/2−
β (20%) Fr
Ra 1769(6) keV 2.1(1) ms IT (99%) Ra 17/2−#
α (1%) Rn
Ra 88 126 214.000108(10) 2.46(3) s α (99.94%) Rn 0+
β (.06%) Fr
Ra 88 127 215.002720(8) 1.55(7) ms α Rn (9/2+)#
Ra 1877.8(5) keV 7.1(2) μs (25/2+)
Ra 2246.9(5) keV 1.39(7) μs (29/2−)
Ra 3756.6(6)+X keV 0.555(10) μs (43/2−)
Ra 88 128 216.003533(9) 182(10) ns α Rn 0+
EC (<1×10%) Fr
Ra 88 129 217.006320(9) 1.63(17) μs α Rn (9/2+)
Ra 88 130 218.007140(12) 25.2(3) μs α Rn 0+
Ra 88 131 219.010085(9) 10(3) ms α Rn (7/2)+
Ra 88 132 220.011028(10) 17.9(14) ms α Rn 0+
Ra 88 133 221.013917(5) 28(2) s α Rn 5/2+ Trace
CD (1.2×10%) Pb
C
Ra 88 134 222.015375(5) 38.0(5) s α Rn 0+
CD (3×10%) Pb
C
Ra Actinium X 88 135 223.0185022(27) 11.43(5) d α Rn 3/2+ Trace
CD (6.4×10%) Pb
C
Ra Thorium X 88 136 224.0202118(24) 3.6319(23) d α Rn 0+ Trace
CD (4.3×10%) Pb
C
Ra 88 137 225.023612(3) 14.9(2) d β Ac 1/2+ Trace
α (2.0×10%) Rn
Ra Radium 88 138 226.0254098(25) 1600(7) y α Rn 0+ Trace
CD (2.6×10%) Pb
C
Ra 88 139 227.0291778(25) 42.2(5) min β Ac 3/2+
Ra Mesothorium 1 88 140 228.0310703(26) 5.75(3) y β Ac 0+ Trace
Ra 88 141 229.034958(20) 4.0(2) min β Ac 5/2(+)
Ra 88 142 230.037056(13) 93(2) min β Ac 0+
Ra 88 143 231.04122(32)# 103(3) s β Ac (5/2+)
Ra 66.21(9) keV ~53 μs (1/2+)
Ra 88 144 232.04364(30)# 250(50) s β Ac 0+
Ra 88 145 233.04806(50)# 30(5) s β Ac 1/2+#
Ra 88 146 234.05070(53)# 30(10) s β Ac 0+
This table header & footer:
  1. Ra – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Modes of decay:
    CD: Cluster decay
    EC: Electron capture
    IT: Isomeric transition
  5. Bold symbol as daughter – Daughter product is stable.
  6. ( ) spin value – Indicates spin with weak assignment arguments.
  7. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  8. Intermediate decay product of Np
  9. Lightest known nuclide to undergo cluster decay
  10. Used for treating bone cancer
  11. Intermediate decay product of U
  12. ^ Intermediate decay product of Th
  13. Intermediate decay product of Np
  14. Source of element's name
  15. Theoretically capable of ββ decay to Th
  16. Intermediate decay product of U

Actinides vs fission products

Actinides and fission products by half-life
Actinides by decay chain Half-life
range (a)
Fission products of U by yield
4n 4n + 1 4n + 2 4n + 3 4.5–7% 0.04–1.25% <0.001%
Ra 4–6 a Eu
Bk > 9 a
Cm Pu Cf Ac 10–29 a Sr Kr Cd
U Pu Cm 29–97 a Cs Sm Sn
Cf Am 141–351 a

No fission products have a half-life
in the range of 100 a–210 ka ...

Am Cf 430–900 a
Ra Bk 1.3–1.6 ka
Pu Th Cm Am 4.7–7.4 ka
Cm Cm 8.3–8.5 ka
Pu 24.1 ka
Th Pa 32–76 ka
Np U U 150–250 ka Tc Sn
Cm Pu 327–375 ka Se
1.33 Ma Cs
Np 1.61–6.5 Ma Zr Pd
U Cm 15–24 Ma I
Pu 80 Ma

... nor beyond 15.7 Ma

Th U U 0.7–14.1 Ga

References

  1. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. ^ Liang, C. F.; Paris, P.; Sheline, R. K. (2000-09-19). "α decay of Ra". Physical Review C. 62 (4). American Physical Society (APS): 047303. Bibcode:2000PhRvC..62d7303L. doi:10.1103/physrevc.62.047303. ISSN 0556-2813.
  3. Nagel, Miriam C. (September 1982). "Frederick Soddy: From alchemy to isotopes". Journal of Chemical Education. 59 (9): 739. Bibcode:1982JChEd..59..739N. doi:10.1021/ed059p739. ISSN 0021-9584.
  4. Kirby, H.W. & Salutsky, Murrell L. (December 1964). The Radiochemistry of Radium (Report). crediting UNT Libraries Government Documents Department. p. 3 – via University of North Texas, UNT Digital Library. Alternate source: https://sgp.fas.org/othergov/doe/lanl/lib-www/books/rc000041.pdf
  5. Giunta, Carmen J. (2017). "ISOTOPES: IDENTIFYING THE BREAKTHROUGH PUBLICATION (1)" (PDF). Bull. Hist. Chem. 42 (2): 103–111.
  6. Looney, William B. (1958). "Effects of Radium in Man". Science. 127 (3299): 630–633. Bibcode:1958Sci...127..630L. doi:10.1126/science.127.3299.630. ISSN 0036-8075. JSTOR 1755774. PMID 13529029.
  7. Mitchell, S. A. "Is Radium in the Sun?". Popular Astronomy. 21: 321–331. Bibcode:1913PA.....21..321M.
  8. Kuhn, W. (1929). "LXVIII. Scattering of thorium C" γ-radiation by radium G and ordinary lead". The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science. 8 (52): 628. doi:10.1080/14786441108564923. ISSN 1941-5982.
  9. Kinsey, R. R. (December 18, 1997), "The radioactive series of radium-226" (PDF), The NUDAT/PCNUDAT Program for Nuclear Data – via CERN
  10. Hills, Stephanie (8 May 2013). "First observations of short-lived pear-shaped atomic nuclei". CERN.
  11. ^ Kalaninová, Z.; Antalic, S.; Andreyev, A. N.; Heßberger, F. P.; Ackermann, D.; Andel, B.; Bianco, L.; Hofmann, S.; Huyse, M.; Kindler, B.; Lommel, B.; Mann, R.; Page, R. D.; Sapple, P. J.; Thomson, J.; Van Duppen, P.; Venhart, M. (12 May 2014). "Decay of Ra and Fr" (PDF). Physical Review C. 89 (5): 054312. Bibcode:2014PhRvC..89e4312K. doi:10.1103/PhysRevC.89.054312. ISSN 0556-2813. Retrieved 11 June 2023.
  12. Uusitalo, J.; Leino, M.; Enqvist, T.; Eskola, K.; Grahn, T.; Greenlees, P. T.; Jones, P.; Julin, R.; Juutinen, S.; Keenan, A.; Kettunen, H.; Koivisto, H.; Kuusiniemi, P.; Leppänen, A.-P.; Nieminen, P.; Pakarinen, J.; Rahkila, P.; Scholey, C. (11 February 2005). "α decay studies of very neutron-deficient francium and radium isotopes". Physical Review C. 71 (2): 024306. Bibcode:2005PhRvC..71b4306U. doi:10.1103/PhysRevC.71.024306. ISSN 0556-2813.
  13. Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no nuclides have half-lives of at least four years (the longest-lived nuclide in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.
  14. Specifically from thermal neutron fission of uranium-235, e.g. in a typical nuclear reactor.
  15. Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. Bibcode:1965NucPh..71..299M. doi:10.1016/0029-5582(65)90719-4.
    "The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk with a half-life greater than 9 . No growth of Cf was detected, and a lower limit for the β half-life can be set at about 10 . No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 ."
  16. This is the heaviest nuclide with a half-life of at least four years before the "sea of instability".
  17. Excluding those "classically stable" nuclides with half-lives significantly in excess of Th; e.g., while Cd has a half-life of only fourteen years, that of Cd is eight quadrillion years.

Notes

  1. Radium emanation = Rn, Ra A = Po, Ra B = Pb, Ra C = Bi, Ra C1 = Po, Ra C2 = Tl, Ra D = Pb, Ra E = Bi, Ra F = Po, and Ra G = Pb.
Isotopes of the chemical elements
Group 1 2   3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Period Hydrogen and
alkali metals
Alkaline
earth metals
Pnicto­gens Chal­co­gens Halo­gens Noble gases
Isotopes § ListH1 Isotopes § ListHe2
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Isotopes § ListK19 Isotopes § ListCa20 Isotopes § ListSc21 Isotopes § ListTi22 Isotopes § ListV23 Isotopes § ListCr24 Isotopes § ListMn25 Isotopes § ListFe26 Isotopes § ListCo27 Isotopes § ListNi28 Isotopes § ListCu29 Isotopes § ListZn30 Isotopes § ListGa31 Isotopes § ListGe32 Isotopes § ListAs33 Isotopes § ListSe34 Isotopes § ListBr35 Isotopes § ListKr36
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