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Isotopes of rubidium

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Isotopes of rubidium (37Rb)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
Rb synth 1.2575 m β Kr
Rb synth 86.2 d ε Kr
γ
Rb synth 32.9 d ε Kr
β Kr
γ
β Sr
Rb 72.2% stable
Rb synth 18.7 d β Sr
γ
Rb 27.8% 4.923×10 y β Sr
Standard atomic weight Ar°(Rb)
  • 85.4678±0.0003
  • 85.468±0.001 (abridged)

Rubidium (37Rb) has 36 isotopes, with naturally occurring rubidium being composed of just two isotopes; Rb (72.2%) and the radioactive Rb (27.8%).

Rb has a half-life of 4.92×10 years. It readily substitutes for potassium in minerals, and is therefore fairly widespread. Rb has been used extensively in dating rocks; Rb decays to stable strontium-87 by emission of a beta particle (an electron ejected from the nucleus). During fractional crystallization, Sr tends to become concentrated in plagioclase, leaving Rb in the liquid phase. Hence, the Rb/Sr ratio in residual magma may increase over time, resulting in rocks with increasing Rb/Sr ratios with increasing differentiation. The highest ratios (10 or higher) occur in pegmatites. If the initial amount of Sr is known or can be extrapolated, the age can be determined by measurement of the Rb and Sr concentrations and the Sr/Sr ratio. The dates indicate the true age of the minerals only if the rocks have not been subsequently altered. See rubidium–strontium dating for a more detailed discussion.

Other than Rb, the longest-lived radioisotopes are Rb with a half-life of 86.2 days, Rb with a half-life of 33.1 days, and Rb with a half-life of 18.642 days. All other radioisotopes have half-lives less than a day.

Rb is used in some cardiac positron emission tomography scans to assess myocardial perfusion. It has a half-life of 1.273 minutes. It does not exist naturally, but can be made from the decay of Sr.

List of isotopes


Nuclide
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Natural abundance (mole fraction)
Excitation energy Normal proportion Range of variation
Rb 37 35 71.95885(54)# 103(22) ns p Kr 1+#
Rb 37 36 72.950605(44) <81 ns p Kr 3/2−#
Rb 37 37 73.9442659(32) 64.78(3) ms β Kr 0+
Rb 37 38 74.9385732(13) 19.0(12) s β Kr 3/2−
Rb 37 39 75.9350730(10) 36.5(6) s β Kr 1−
β, α (3.8×10%) Se
Rb 316.93(8) keV 3.050(7) μs IT Rb (4+)
Rb 37 40 76.9304016(14) 3.78(4) min β Kr 3/2−
Rb 37 41 77.9281419(35) 17.66(3) min β Kr 0+
Rb 46.84(14) keV 910(40) ns IT Rb (1−)
Rb 111.19(22) keV 5.74(3) min β (91%) Kr 4−
IT (9%) Rb
Rb 37 42 78.9239901(21) 22.9(5) min β Kr 5/2+
Rb 37 43 79.9225164(20) 33.4(7) s β Kr 1+
Rb 493.9(5) keV 1.63(4) μs IT Rb (6+)
Rb 37 44 80.9189939(53) 4.572(4) h β Kr 3/2−
Rb 86.31(7) keV 30.5(3) min IT (97.6%) Rb 9/2+
β (2.4%) Kr
Rb 37 45 81.9182090(32) 1.2575(2) min β Kr 1+
Rb 69.0(15) keV 6.472(6) h β (>99.67%) Kr 5−
IT (<0.33%) Rb
Rb 37 46 82.9151142(25) 86.2(1) d EC Kr 5/2−
Rb 42.0780(20) keV 7.8(7) ms IT Rb 9/2+
Rb 37 47 83.9143752(24) 32.8(07) d β (96.1%) Kr 2−
β (3.9%) Sr
Rb 463.59(8) keV 20.26(4) min IT Rb 6−
β (<0.0012%) Kr
Rb 37 48 84.9117897360(54) Stable 5/2− 0.7217(2)
Rb 514.0065(22) keV 1.015(1) μs IT Rb 9/2+
Rb 37 49 85.91116744(21) 18.645(8) d β (99.99%) Sr 2−
EC (.0052%) Kr
Rb 556.05(18) keV 1.017(3) min IT (>99.7%) Rb 6−
β (<0.3%) Sr
Rb 37 50 86.909180529(6) 4.97(3)×10 y β Sr 3/2− 0.2783(2)
Rb 37 51 87.91131559(17) 17.78(3) min β Sr 2−
Rb 1373.8(3) keV 123(13) ns IT Rb (7+)
Rb 37 52 88.9122781(58) 15.32(10) min β Sr 3/2−
Rb 37 53 89.9147976(69) 158(5) s β Sr 0−
Rb 106.90(3) keV 258(4) s β (97.4%) Sr 3−
IT (2.6%) Rb
Rb 37 54 90.9165373(84) 58.2(3) s β Sr 3/2−
Rb 37 55 91.9197285(66) 4.48(3) s β (99.99%) Sr 0−
β, n (0.0107%) Sr
Rb 37 56 92.9220393(84) 5.84(2) s β (98.61%) Sr 5/2−
β, n (1.39%) Sr
Rb 4423.1(15) keV 111(11) ns IT Rb (27/2−)
Rb 37 57 93.9263948(22) 2.702(5) s β (89.7%) Sr 3−
β, n (10.3%) Sr
Rb 104.2(2) keV 130(15) ns IT Rb (0−)
Rb 2074.9(14) keV 107(16) ns IT Rb (10−)
Rb 37 58 94.929264(22) 377.7(8) ms β (91.3%) Sr 5/2−
β, n (8.7%) Sr
Rb 835.0(6) keV <500 ns IT Rb 9/2+#
Rb 37 59 95.9341334(36) 201.5(9) ms β (86.3%) Sr 2−
β, n (13.7%) Sr
Rb 0(200)# keV 200# ms
1(+#)
Rb 1134.6(11) keV 1.80(4) μs IT Rb (10−)
Rb 37 60 96.9371771(21) 169.1(6) ms β (74.5%) Sr 3/2+
β, n (25.5%) Sr
Rb 76.6(2) keV 5.7(6) μs IT Rb (1/2,3/2)−
Rb 37 61 97.941632(17) 115(6) ms β(85.65%) Sr (0−)
β, n (14.3%) Sr
β, 2n (0.054%) Sr
Rb 73(26) keV 96(3) ms β Sr (3+)
Rb 178.5(4) keV 358(7) ns IT Rb (2−)
Rb 37 62 98.9451192(43) 54(4) ms β (82.7%) Sr (3/2+)
β, n (17.3%) Sr
Rb 37 63 99.950332(14) 51.3(16) ms β (94.3%) Sr 4−#
β, n (5.6%) Sr
β, 2n (0.15%) Sr
Rb 37 64 100.954302(22) 31.8(33) ms β (72%) Sr 3/2+#
β, n (28%) Sr
Rb 37 65 101.960008(89) 37(4) ms β, n (65%) Sr (4+)
β (35%) Sr
Rb 37 66 102.96440(43)# 26(11) ms β Sr 3/2+#
Rb 37 67 103.97053(54)# 35# ms
Rb 37 68
Rb 37 69
This table header & footer:
  1. Rb – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Bold half-life – nearly stable, half-life longer than age of universe.
  5. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  6. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  7. Bold italics symbol as daughter – Daughter product is nearly stable.
  8. Bold symbol as daughter – Daughter product is stable.
  9. ( ) spin value – Indicates spin with weak assignment arguments.
  10. ^ Fission product
  11. Primordial radionuclide
  12. Used in rubidium–strontium dating
  13. Order of ground state and isomer is uncertain.

Rubidium-87

Rubidium-87 was the first and the most popular atom for making Bose–Einstein condensates in dilute atomic gases. Even though rubidium-85 is more abundant, rubidium-87 has a positive scattering length, which means it is mutually repulsive, at low temperatures. This prevents a collapse of all but the smallest condensates. It is also easy to evaporatively cool, with a consistent strong mutual scattering. There is also a strong supply of cheap uncoated diode lasers typically used in CD writers, which can operate at the correct wavelength.

Rubidium-87 has an atomic mass of 86.9091835 u, and a binding energy of 757,853 keV. Its atomic percent abundance is 27.835%, and has a half-life of 4.92×10 years.

References

  1. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. "Standard Atomic Weights: Rubidium". CIAAW. 1969.
  3. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  4. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  5. ^ Sumikama, T.; et al. (2021). "Observation of new neutron-rich isotopes in the vicinity of 110Zr". Physical Review C. 103 (1): 014614. Bibcode:2021PhRvC.103a4614S. doi:10.1103/PhysRevC.103.014614. hdl:10261/260248. S2CID 234019083.
Isotopes of the chemical elements
Group 1 2   3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Period Hydrogen and
alkali metals
Alkaline
earth metals
Pnicto­gens Chal­co­gens Halo­gens Noble gases
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