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Isotopes of ruthenium

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Isotopes of ruthenium (44Ru)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
Ru 5.54% stable
Ru synth 2.9 d ε Tc
γ
Ru 1.87% stable
Ru 12.8% stable
Ru 12.6% stable
Ru 17.1% stable
Ru 31.6% stable
Ru synth 39.26 d β Rh
γ
Ru 18.6% stable
Ru synth 373.59 d β Rh
Standard atomic weight Ar°(Ru)

Naturally occurring ruthenium (44Ru) is composed of seven stable isotopes (of which two may in the future be found radioactive). Additionally, 27 radioactive isotopes have been discovered. Of these radioisotopes, the most stable are Ru, with a half-life of 373.59 days; Ru, with a half-life of 39.26 days and Ru, with a half-life of 2.9 days.

Twenty-four other radioisotopes have been characterized with atomic weights ranging from 86.95 u (Ru) to 119.95 u (Ru). Most of these have half-lives that are less than five minutes, except Ru (half-life: 51.8 minutes), Ru (half-life: 1.643 hours), and Ru (half-life: 4.44 hours).

The primary decay mode before the most abundant isotope, Ru, is electron capture and the primary mode after is beta emission. The primary decay product before Ru is technetium and the primary product after is rhodium.

Because of the very high volatility of ruthenium tetroxide (RuO
4) ruthenium radioactive isotopes with their relative short half-life are considered as the second most hazardous gaseous isotopes after iodine-131 in case of release by a nuclear accident. The two most important isotopes of ruthenium in case of nuclear accident are these with the longest half-life: Ru (39.26 days) and Ru (373.59 days).

List of isotopes


Nuclide
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Natural abundance (mole fraction)
Excitation energy Normal proportion Range of variation
Ru 44 43 86.94918(64)# 50# ms β Tc 1/2−#
Ru 44 44 87.94026(43)# 1.3(3) s β Tc 0+
Ru 44 45 88.93611(54)# 1.38(11) s β Tc (7/2)(+#)
Ru 44 46 89.92989(32)# 11.7(9) s β Tc 0+
Ru 44 47 90.92629(63)# 7.9(4) s β Tc (9/2+)
Ru 80(300)# keV 7.6(8) s β (>99.9%) Tc (1/2−)
IT (<.1%) Ru
β, p (<.1%) Mo
Ru 44 48 91.92012(32)# 3.65(5) min β Tc 0+
Ru 44 49 92.91705(9) 59.7(6) s β Tc (9/2)+
Ru 734.40(10) keV 10.8(3) s β (78%) Tc (1/2)−
IT (22%) Ru
β, p (.027%) Mo
Ru 2082.6(9) keV 2.20(17) μs (21/2)+
Ru 44 50 93.911360(14) 51.8(6) min β Tc 0+
Ru 2644.55(25) keV 71(4) μs (8+)
Ru 44 51 94.910413(13) 1.643(14) h β Tc 5/2+
Ru 44 52 95.907598(8) Observationally Stable 0+ 0.0554(14)
Ru 44 53 96.907555(9) 2.791(4) d β Tc 5/2+
Ru 44 54 97.905287(7) Stable 0+ 0.0187(3)
Ru 44 55 98.9059393(22) Stable 5/2+ 0.1276(14)
Ru 44 56 99.9042195(22) Stable 0+ 0.1260(7)
Ru 44 57 100.9055821(22) Stable 5/2+ 0.1706(2)
Ru 527.56(10) keV 17.5(4) μs 11/2−
Ru 44 58 101.9043493(22) Stable 0+ 0.3155(14)
Ru 44 59 102.9063238(22) 39.26(2) d β Rh 3/2+
Ru 238.2(7) keV 1.69(7) ms IT Ru 11/2−
Ru 44 60 103.905433(3) Observationally Stable 0+ 0.1862(27)
Ru 44 61 104.907753(3) 4.44(2) h β Rh 3/2+
Ru 44 62 105.907329(8) 373.59(15) d β Rh 0+
Ru 44 63 106.90991(13) 3.75(5) min β Rh (5/2)+
Ru 44 64 107.91017(12) 4.55(5) min β Rh 0+
Ru 44 65 108.91320(7) 34.5(10) s β Rh (5/2+)#
Ru 44 66 109.91414(6) 11.6(6) s β Rh 0+
Ru 44 67 110.91770(8) 2.12(7) s β Rh (5/2+)
Ru 44 68 111.91897(8) 1.75(7) s β Rh 0+
Ru 44 69 112.92249(8) 0.80(5) s β Rh (5/2+)
Ru 130(18) keV 510(30) ms (11/2−)
Ru 44 70 113.92428(25)# 0.53(6) s β (>99.9%) Rh 0+
β, n (<.1%) Rh
Ru 44 71 114.92869(14) 740(80) ms β (>99.9%) Rh
β, n (<.1%) Rh
Ru 44 72 115.93081(75)# 400# ms β Rh 0+
Ru 44 73 116.93558(75)# 300# ms β Rh
Ru 44 74 117.93782(86)# 200# ms β Rh 0+
Ru 44 75 118.94284(75)# 170# ms
Ru 44 76 119.94531(86)# 80# ms 0+
This table header & footer:
  1. Ru – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. Modes of decay:
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  6. Bold symbol as daughter – Daughter product is stable.
  7. ( ) spin value – Indicates spin with weak assignment arguments.
  8. Believed to undergo ββ decay to Mo with a half-life over 6.7×10 years
  9. ^ Fission product
  10. Believed to undergo ββ decay to Pd
  • Geologically exceptional samples are known in which the isotopic composition lies outside the reported range. The uncertainty in the atomic mass may exceed the stated value for such specimens.
  • In September 2017 an estimated amount of 100 to 300 TBq (0.3 to 1 g) of Ru was released in Russia, probably in the Ural region. It was, after ruling out release from a reentering satellite, concluded that the source is to be found either in nuclear fuel cycle facilities or radioactive source production. In France levels up to 0.036mBq/m of air were measured. It is estimated that over distances of the order of a few tens of kilometres around the location of the release levels may exceed the limits for non-dairy foodstuffs.
Ruthenium-96

References

  1. Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. "Standard Atomic Weights: Ruthenium". CIAAW. 1983.
  3. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  4. Ronneau, C., Cara, J., & Rimski-Korsakov, A. (1995). Oxidation-enhanced emission of ruthenium from nuclear fuel. Journal of Environmental Radioactivity, 26(1), 63-70.
  5. ^ Backman, U., Lipponen, M., Auvinen, A., Jokiniemi, J., & Zilliacus, R. (2004). Ruthenium behaviour in severe nuclear accident conditions. Final report (No. NKS–100). Nordisk Kernesikkerhedsforskning.
  6. Beuzet, E., Lamy, J. S., Perron, H., Simoni, E., & Ducros, G. (2012). Ruthenium release modelling in air and steam atmospheres under severe accident conditions using the MAAP4 code. Nuclear Engineering and Design, 246, 157-162.
  7. Detection of ruthenium 106 in France and in Europe, IRSN France (9 Nov 2017)
Isotopes of the chemical elements
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