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Isotopes of silver

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Isotopes of silver (47Ag)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
Ag synth 41.3 d ε Pd
γ
Ag synth 8.28 d ε Pd
γ
Ag 51.8% stable
Ag synth 439 y ε Pd
IT Ag
γ
Ag 48.2% stable
Ag synth 249.86 d β Cd
γ
Ag synth 7.43 d β Cd
γ
Standard atomic weight Ar°(Ag)
  • 107.8682±0.0002
  • 107.87±0.01 (abridged)

Naturally occurring silver (47Ag) is composed of the two stable isotopes Ag and Ag in almost equal proportions, with Ag being slightly more abundant (51.839% natural abundance). Notably, silver is the only element with all stable istopes having nuclear spins of 1/2. Thus both Ag and Ag nuclei produce narrow lines in nuclear magnetic resonance spectra.

40 radioisotopes have been characterized with the most stable being Ag with a half-life of 41.29 days, Ag with a half-life of 7.43 days, and Ag with a half-life of 3.13 hours.

All of the remaining radioactive isotopes have half-lives that are less than an hour, and the majority of these have half-lives that are less than 3 minutes. This element has numerous meta states, with the most stable being Ag (half-life 439 years), Ag (half-life 249.86 days) and Ag (half-life 8.28 days).

Isotopes of silver range in atomic weight from Ag to Ag. The primary decay mode before the most abundant stable isotope, Ag, is electron capture and the primary mode after is beta decay. The primary decay products before Ag are palladium (element 46) isotopes and the primary products after are cadmium (element 48) isotopes.

The palladium isotope Pd decays by beta emission to Ag with a half-life of 6.5 million years. Iron meteorites are the only objects with a high enough palladium/silver ratio to yield measurable variations in Ag abundance. Radiogenic Ag was first discovered in the Santa Clara meteorite in 1978.

The discoverers suggest that the coalescence and differentiation of iron-cored small planets may have occurred 10 million years after a nucleosynthetic event. Pd versus Ag correlations observed in bodies, which have clearly been melted since the accretion of the Solar System, must reflect the presence of live short-lived nuclides in the early Solar System.

List of isotopes


Nuclide
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Natural abundance (mole fraction)
Excitation energy Normal proportion Range of variation
Ag 47 45 91.95971(43)# 1# ms
β? Pd
p? Pd
Ag 47 46 92.95019(43)# 228(16) ns β? Pd 9/2+#
p? Pd
β, p? Rh
Ag 47 47 93.94374(43)# 27(2) ms β (>99.8%) Pd 0+#
β, p (<0.2%) Rh
Ag 1350(400)# keV 470(10) ms β (83%) Pd (7+)
β, p (17%) Rh
Ag 6500(550)# keV 400(40) ms β (~68.4%) Pd (21+)
β, p (~27%) Rh
p (4.1%) Pd
2p (0.5%) Rh
Ag 47 48 94.93569(43)# 1.78(6) s β (97.7%) Pd (9/2+)
β, p (2.3%) Rh
Ag 344.2(3) keV <0.5 s IT Ag (1/2−)
Ag 2531.3(15) keV <16 ms IT Ag (23/2+)
Ag 4860.0(15) keV <40 ms IT Ag (37/2+)
Ag 47 49 95.93074(10) 4.45(3) s β (95.8%) Pd (8)+
β, p (4.2%) Rh
Ag 0(50)# keV 6.9(5) s β (85.1%) Pd (2+)
β, p (14.9%) Rh
Ag 2461.4(3) keV 103.2(45) μs IT Ag (13−)
Ag 2686.7(4) keV 1.561(16) μs IT Ag (15+)
Ag 6951.8(14) keV 132(17) ns IT Ag (19+)
Ag 47 50 96.923881(13) 25.5(3) s β Pd (9/2)+
Ag 620(40) keV 100# ms IT? Ag 1/2−#
Ag 47 51 97.92156(4) 47.5(3) s β Pd (6)+
β, p (.0012%) Rh
Ag 107.28(10) keV 161(7) ns IT Ag (4+)
Ag 47 52 98.917646(7) 2.07(5) min β Pd (9/2)+
Ag 506.2(4) keV 10.5(5) s IT Ag (1/2−)
Ag 47 53 99.916115(5) 2.01(9) min β Pd (5)+
Ag 15.52(16) keV 2.24(13) min IT? Ag (2)+
β? Pd
Ag 47 54 100.912684(5) 11.1(3) min β Pd 9/2+
Ag 274.1(3) keV 3.10(10) s IT Ag (1/2)−
Ag 47 55 101.911705(9) 12.9(3) min β Pd 5+
Ag 9.40(7) keV 7.7(5) min β (51%) Pd 2+
IT (49%) Ag
Ag 47 56 102.908961(4) 65.7(7) min β Pd 7/2+
Ag 134.45(4) keV 5.7(3) s IT Ag 1/2−
Ag 47 57 103.908624(5) 69.2(10) min β Pd 5+
Ag 6.90(22) keV 33.5(20) min β (>99.93%) Pd 2+
IT (<0.07%) Ag
Ag 47 58 104.906526(5) 41.29(7) d β Pd 1/2−
Ag 25.468(16) keV 7.23(16) min IT (99.66%) Ag 7/2+
β (.34%) Pd
Ag 47 59 105.906663(3) 23.96(4) min β Pd 1+
β? Cd
Ag 89.66(7) keV 8.28(2) d β Pd 6+
IT? Ag
Ag 47 60 106.9050915(26) Stable 1/2− 0.51839(8)
Ag 93.125(19) keV 44.3(2) s IT Ag 7/2+
Ag 47 61 107.9059502(26) 2.382(11) min β (97.15%) Cd 1+
EC (2.57%) Pd
β (0.283%) Pd
Ag 109.466(7) keV 439(9) y EC (91.3%) Pd 6+
IT (8.96%) Ag
Ag 47 62 108.9047558(14) Stable 1/2− 0.48161(8)
Ag 88.0337(10) keV 39.79(21) s IT Ag 7/2+
Ag 47 63 109.9061107(14) 24.56(11) s β (99.70%) Cd 1+
EC (0.30%) Pd
Ag 1.112(16) keV 660(40) ns IT Ag 2−
Ag 117.59(5) keV 249.863(24) d β (98.67%) Cd 6+
IT (1.33%) Ag
Ag 47 64 110.9052968(16) 7.433(10) d β Cd 1/2−
Ag 59.82(4) keV 64.8(8) s IT (99.3%) Ag 7/2+
β (0.7%) Cd
Ag 47 65 111.9070485(26) 3.130(8) h β Cd 2(−)
Ag 47 66 112.906573(18) 5.37(5) h β Cd 1/2−
Ag 43.50(10) keV 68.7(16) s IT (64%) Ag 7/2+
β (36%) Cd
Ag 47 67 113.908823(5) 4.6(1) s β Cd 1+
Ag 198.9(10) keV 1.50(5) ms IT Ag (6+)
Ag 47 68 114.908767(20) 20.0(5) min β Cd 1/2−
Ag 41.16(10) keV 18.0(7) s β (79.0%) Cd 7/2+
IT (21.0%) Ag
Ag 47 69 115.911387(4) 3.83(8) min β Cd (0−)
Ag 47.90(10) keV 20(1) s β (93%) Cd (3+)
IT (7%) Ag
Ag 129.80(22) keV 9.3(3) s β (92%) Cd (6−)
IT (8%) Ag
Ag 47 70 116.911774(15) 73.6(14) s β Cd 1/2−#
Ag 28.6(2) keV 5.34(5) s β (94.0%) Cd 7/2+#
IT (6.0%) Ag
Ag 47 71 117.9145955(27) 3.76(15) s β Cd (2−)
Ag 45.79(9) keV ~0.1 μs IT Ag (1,2)−
Ag 127.63(10) keV 2.0(2) s β (59%) Cd (5+)
IT (41%) Ag
Ag 279.37(20) keV ~0.1 μs IT Ag (3+)
Ag 47 72 118.915570(16) 2.1(1) s β Cd (7/2+)
Ag 33.5(3) keV 6.0(5) s β Cd (1/2−)
Ag 47 73 119.918785(5) 1.52(7) s β Cd 4(+)
β, n (<.003%) Cd
Ag 0(50)# keV 940(100) ms β? Cd (0−, 1−)
IT? Ag
β, n? Cd
Ag 203.2(2) keV 384(22) ms IT (68%) Sn 7(−)
β (32%) Cd
β, n? Cd
Ag 47 74 120.920125(13) 777(10) ms β (99.92%) Cd 7/2+#
β, n (0.080%) Cd
Ag 47 75 121.9235420(56) 550(50) ms β Cd (1−)
β, n? Cd
Ag 303.7(50) keV 200(50) ms β Cd (9−)
β, n? Cd
IT? Ag
Ag 171(50)# keV 6.3(1) μs IT Ag (1+)
Ag 47 76 122.92532(4) 294(5) ms β (99.44%) Cd (7/2+)
β, n (0.56%) Cd
Ag 59.5(5) keV 100# ms β Cd (1/2−)
β, n? Cd
Ag 1450(14)# keV 202(20) ns IT Ag
Ag 1472.8(8) keV 393(16) ns IT Ag (17/2−)
Ag 47 77 123.92890(27)# 177.9(26) ms β (98.7%) Cd (2−)
β, n (1.3%) Cd
Ag 50(50)# keV 144(20) ms β Cd 9−#
β, n? Cd
Ag 155.6(5) keV 140(50) ns IT Ag (1+)
Ag 231.1(7) keV 1.48(15) μs IT Ag (1−)
Ag 47 78 124.93074(47) 160(5) ms β (88.2%) Cd (9/2+)
β, n (11.8%) Cd
Ag 97.1(5) keV 50# ms β? Cd (1/2−)
IT? Ag
β, n? Cd
Ag 1501.2(6) keV 491(20) ns IT Ag (17/2−)
Ag 47 79 125.93481(22)# 52(10) ms β (86.3%) Cd 3+#
β, n (13.7%) Cd
Ag 100(100)# keV 108.4(24) ms β Cd 9−#
IT? Ag
β, n? Cd
Ag 254.8(5) keV 27(6) μs IT Ag 1−#
Ag 47 80 126.93704(22)# 89(2) ms β (85.4%) Cd (9/2+)
β, n (14.6%) Cd
Ag 1938(17) keV 67.5(9) ms β (91.2%) Cd (27/2+)
IT (8.8%) Ag
Ag 47 81 127.94127(32)# 60(3) ms β (80%) Cd 3+#
β, n (20%) Cd
β, 2n? Cd
Ag 47 82 128.94432(43)# 49.9(35) ms β (>80%) Cd 9/2+#
β, n (<20%) Cd
Ag 47 83 129.95073(46)# 40.6(45) ms β Cd 1−#
β, n? Cd
β, 2n? Cd
Ag 47 84 130.95625(54)# 35(8) ms β (90%) Cd 9/2+#
β, 2n (10%) Cd
β, n? Cd
Ag 47 85 131.96307(54)# 30(14) ms β Cd 6−#
β, n? Cd
β, 2n? Cd
This table header & footer:
  1. Ag – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  6. Bold italics symbol as daughter – Daughter product is nearly stable.
  7. Bold symbol as daughter – Daughter product is stable.
  8. ( ) spin value – Indicates spin with weak assignment arguments.
  9. ^ Order of ground state and isomer is uncertain.
  10. Used to date certain events in the early history of the Solar System
  11. ^ Fission product

References

  1. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. "Standard Atomic Weights: Silver". CIAAW. 1985.
  3. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  4. "(Ag) Silver NMR".
  5. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  6. ^ Blachot, Jean (October 2000). "Nuclear Data Sheets for A = 108". Nuclear Data Sheets. 91 (2): 135–296. doi:10.1006/ndsh.2000.0017.
  7. Kurpeta, J.; Abramuk, A.; Rząca-Urban, T.; Urban, W.; Canete, L.; Eronen, T.; Geldhof, S.; Gierlik, M.; Greene, J. P.; Jokinen, A.; Kankainen, A.; Moore, I. D.; Nesterenko, D. A.; Penttilä, H.; Pohjalainen, I.; Reponen, M.; Rinta-Antila, S.; de Roubin, A.; Simpson, G. S.; Smith, A. G.; Vilén, M. (14 March 2022). "β - and γ -spectroscopy study of Pd 119 and Ag 119". Physical Review C. 105 (3). doi:10.1103/PhysRevC.105.034316.
  8. ^ Jaries, A.; Stryjczyk, M.; Kankainen, A.; Ayoubi, L. Al; Beliuskina, O.; Canete, L.; de Groote, R. P.; Delafosse, C.; Delahaye, P.; Eronen, T.; Flayol, M.; Ge, Z.; Geldhof, S.; Gins, W.; Hukkanen, M.; Imgram, P.; Kahl, D.; Kostensalo, J.; Kujanpää, S.; Kumar, D.; Moore, I. D.; Mougeot, M.; Nesterenko, D. A.; Nikas, S.; Patel, D.; Penttilä, H.; Pitman-Weymouth, D.; Pohjalainen, I.; Raggio, A.; Ramalho, M.; Reponen, M.; Rinta-Antila, S.; de Roubin, A.; Ruotsalainen, J.; Srivastava, P. C.; Suhonen, J.; Vilen, M.; Virtanen, V.; Zadvornaya, A. "Physical Review C - Accepted Paper: Isomeric states of fission fragments explored via Penning trap mass spectrometry at IGISOL". journals.aps.org. arXiv:2403.04710.
Isotopes of the chemical elements
Group 1 2   3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Period Hydrogen and
alkali metals
Alkaline
earth metals
Pnicto­gens Chal­co­gens Halo­gens Noble gases
Isotopes § ListH1 Isotopes § ListHe2
Isotopes § ListLi3 Isotopes § ListBe4 Isotopes § ListB5 Isotopes § ListC6 Isotopes § ListN7 Isotopes § ListO8 Isotopes § ListF9 Isotopes § ListNe10
Isotopes § ListNa11 Isotopes § ListMg12 Isotopes § ListAl13 Isotopes § ListSi14 Isotopes § ListP15 Isotopes § ListS16 Isotopes § ListCl17 Isotopes § ListAr18
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Isotopes § ListRb37 Isotopes § ListSr38 Isotopes § ListY39 Isotopes § ListZr40 Isotopes § ListNb41 Isotopes § ListMo42 Isotopes § ListTc43 Isotopes § ListRu44 Isotopes § ListRh45 Isotopes § ListPd46 Isotopes § ListAg47 Isotopes § ListCd48 Isotopes § ListIn49 Isotopes § ListSn50 Isotopes § ListSb51 Isotopes § ListTe52 Isotopes § ListI53 Isotopes § ListXe54
Isotopes § ListCs55 Isotopes § ListBa56 1 asterisk Isotopes § ListLu71 Isotopes § ListHf72 Isotopes § ListTa73 Isotopes § ListW74 Isotopes § ListRe75 Isotopes § ListOs76 Isotopes § ListIr77 Isotopes § ListPt78 Isotopes § ListAu79 Isotopes § ListHg80 Isotopes § ListTl81 Isotopes § ListPb82 Isotopes § ListBi83 Isotopes § ListPo84 Isotopes § ListAt85 Isotopes § ListRn86
Isotopes § ListFr87 Isotopes § ListRa88 1 asterisk Isotopes § ListLr103 Isotopes § ListRf104 Isotopes § ListDb105 Isotopes § ListSg106 Isotopes § ListBh107 Isotopes § ListHs108 Isotopes § ListMt109 Isotopes § ListDs110 Isotopes § ListRg111 Isotopes § ListCn112 Isotopes § ListNh113 Isotopes § ListFl114 Isotopes § ListMc115 Isotopes § ListLv116 Isotopes § ListTs117 Isotopes § ListOg118
Isotopes § ListUue119 Isotopes § ListUbn120
1 asterisk Isotopes § ListLa57 Isotopes § ListCe58 Isotopes § ListPr59 Isotopes § ListNd60 Isotopes § ListPm61 Isotopes § ListSm62 Isotopes § ListEu63 Isotopes § ListGd64 Isotopes § ListTb65 Isotopes § ListDy66 Isotopes § ListHo67 Isotopes § ListEr68 Isotopes § ListTm69 Isotopes § ListYb70  
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