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Strontium oxide

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Strontium oxide
__ Sr2+     __ O2−
Names
IUPAC name Strontium oxide
Other names Strontia
Identifiers
CAS Number
3D model (JSmol)
ECHA InfoCard 100.013.837 Edit this at Wikidata
EC Number
  • 215-219-9
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/O.Sr/q-2;+2
SMILES
  • .
Properties
Chemical formula SrO
Molar mass 103.619 g/mol
Appearance colorless cubic crystals
Density 4.70 g/cm
Melting point 2,531 °C (4,588 °F; 2,804 K)
Boiling point 3,200 °C (5,790 °F; 3,470 K) (decomposes)
Solubility in water reacts, forms Sr(OH)2
Solubility miscible with potassium hydroxide
slightly soluble in alcohol
insoluble in acetone and ether
Magnetic susceptibility (χ) −35.0·10 cm/mol
Refractive index (nD) 1.810
Structure
Crystal structure Halite (cubic), cF8
Space group Fm3m, No. 225
Coordination geometry Octahedral (Sr); octahedral (O)
Thermochemistry
Heat capacity (C) 44.3 J·mol·K
Std molar
entropy
(S298)
57.2 J·mol·K
Std enthalpy of
formation
fH298)
-592.0 kJ·mol
Hazards
Flash point Non-flammable
Related compounds
Other anions Strontium sulfide
Other cations Beryllium oxide
Magnesium oxide
Calcium oxide
Barium oxide
Related compounds Strontium hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). ☒verify (what is  ?) Infobox references
Chemical compound

Strontium oxide or strontia, SrO, is formed when strontium reacts with oxygen. Burning strontium in air results in a mixture of strontium oxide and strontium nitride. It also forms from the decomposition of strontium carbonate SrCO3. It is a strongly basic oxide.

Uses

About 8% by weight of cathode ray tubes is strontium oxide, which has been the major use of strontium since 1970. Color televisions and other devices containing color cathode ray tubes sold in the United States are required by law to use strontium in the faceplate to block X-ray emission (these X-ray emitting TVs are no longer in production). Lead(II) oxide can be used in the neck and funnel, but causes discoloration when used in the faceplate.

Reactions

Elemental strontium is formed when strontium oxide is heated with aluminium in a vacuum.

References

  1. ^ Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, Florida: CRC Press. pp. 4–87. ISBN 0-8493-0594-2.
  2. Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0-07-049439-8
  3. Ober, Joyce A.; Polyak, Désirée E. "Mineral Yearbook 2007:Strontium" (PDF). United States Geological Survey. Retrieved 2009-09-14.
  4. Minerals Yearbook. Bureau of Mines. May 8, 2011. ISBN 9781411332270 – via Google Books.
  5. Méar, F; Yot, P; Cambon, M; Ribes, M (2006). "The characterization of waste cathode-ray tube glass". Waste Management. 26 (12): 1468–76. Bibcode:2006WaMan..26.1468M. doi:10.1016/j.wasman.2005.11.017. ISSN 0956-053X. PMID 16427267.

External links

Strontium compounds
Oxides
Mixed oxidation states
+1 oxidation state
+2 oxidation state
+3 oxidation state
+4 oxidation state
+5 oxidation state
+6 oxidation state
+7 oxidation state
+8 oxidation state
Related
Oxides are sorted by oxidation state. Category:Oxides
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