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Tetraethylammonium tetrachloronickelate

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Tetraethylammonium tetrachloronickelate

(Et4N)2NiCl4 crystals
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.152.710 Edit this at Wikidata
EC Number
  • 624-087-5
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/2C8H20N.4ClH.Ni/c2*1-5-9(6-2,7-3)8-4;;;;;/h2*5-8H2,1-4H3;4*1H;/q2*+1;;;;;+2/p-4Key: LBROWQNNUGFYKG-UHFFFAOYSA-J
SMILES
  • CC(CC)(CC)CC.CC(CC)(CC)CC.Cl()()Cl
Properties
Chemical formula C16H40Cl4N2Ni
Molar mass 461.00 g·mol
Appearance blue solid
Density 1.358 g/cm
Hazards
GHS labelling:
Pictograms GHS05: CorrosiveGHS07: Exclamation markGHS09: Environmental hazard
Signal word Danger
Hazard statements H314, H317, H350
Precautionary statements P201, P202, P260, P261, P264, P272, P280, P281, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P321, P333+P313, P363, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Tetraethylammonium tetrachloronickelate is the chemical compound with the formula (N(C2H5)4)2NiCl4. It is the tetraethylammonium salt of the blue-colored tetrahedral anion . Several tetrachloronickelate salts are known. They are paramagnetic.

References

  1. Naida S. Gill; F. B. Taylor (1967). "Tetrahalo Complexes of Dipositive Metals in the First Transition Series". Inorganic Syntheses. Vol. 9. pp. 136–142. doi:10.1002/9780470132401.ch37. ISBN 978-0-470-13168-8.
  2. Stucky, G. D.; Folkers, J. B.; Kistenmacher, T. J. (1967). "The Crystal and Molecular Structure of Tetraethylammonium Tetrachloronickelate(II)". Acta Crystallographica. 23 (6): 1064–1070. Bibcode:1967AcCry..23.1064S. doi:10.1107/S0365110X67004268.
Salts and covalent derivatives of the chloride ion
HCl He
LiCl BeCl2 B4Cl4
B12Cl12
BCl3
B2Cl4
+BO3
C2Cl2
C2Cl4
C2Cl6
CCl4
+C
+CO3
NCl3
ClN3
+N
+NO3
ClxOy
Cl2O
Cl2O2
ClO
ClO2
Cl2O4
Cl2O6
Cl2O7
ClO4
+O
ClF
ClF3
ClF5
Ne
NaCl MgCl2 AlCl
AlCl3
Si5Cl12
Si2Cl6
SiCl4
P2Cl4
PCl3
PCl5
+P
S2Cl2
SCl2
SCl4
+SO4
Cl2 Ar
KCl CaCl
CaCl2
ScCl3 TiCl2
TiCl3
TiCl4
VCl2
VCl3
VCl4
VCl5
CrCl2
CrCl3
CrCl4
MnCl2
MnCl3
FeCl2
FeCl3
CoCl2
CoCl3
NiCl2 CuCl
CuCl2
ZnCl2 GaCl
GaCl3
GeCl2
GeCl4
AsCl3
AsCl5
+As
Se2Cl2
SeCl2
SeCl4
BrCl Kr
RbCl SrCl2 YCl3 ZrCl2
ZrCl3
ZrCl4
NbCl3
NbCl4
NbCl5
MoCl2
MoCl3
MoCl4
MoCl5
MoCl6
TcCl3
TcCl4
RuCl2
RuCl3
RuCl4
RhCl3 PdCl2 AgCl CdCl2 InCl
InCl2
InCl3
SnCl2
SnCl4
SbCl3
SbCl5
Te3Cl2
TeCl2
TeCl4
ICl
ICl3
XeCl
XeCl2
XeCl4
CsCl BaCl2 * LuCl3 HfCl4 TaCl3
TaCl4
TaCl5
WCl2
WCl3
WCl4
WCl5
WCl6
ReCl3
ReCl4
ReCl5
ReCl6
OsCl2
OsCl3
OsCl4
OsCl5
IrCl2
IrCl3
IrCl4
PtCl2
PtCl4
AuCl
(Au)2
AuCl3
Hg2Cl2
HgCl2
TlCl
TlCl3
PbCl2
PbCl4
BiCl3 PoCl2
PoCl4
AtCl Rn
FrCl RaCl2 ** LrCl3 RfCl4 DbCl5 SgO2Cl2 BhO3Cl Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaCl3 CeCl3 PrCl3 NdCl2
NdCl3
PmCl3 SmCl2
SmCl3
EuCl2
EuCl3
GdCl3 TbCl3 DyCl2
DyCl3
HoCl3 ErCl3 TmCl2
TmCl3
YbCl2
YbCl3
** AcCl3 ThCl3
ThCl4
PaCl4
PaCl5
UCl3
UCl4
UCl5
UCl6
NpCl3 PuCl3 AmCl2
AmCl3
CmCl3 BkCl3 CfCl3
CfCl2
EsCl2
EsCl3
FmCl2 MdCl2 NoCl2
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