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Isotopes of titanium

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Isotopes of titanium (22Ti)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
Ti synth 59.1 y ε Sc
Ti 8.25% stable
Ti 7.44% stable
Ti 73.7% stable
Ti 5.41% stable
Ti 5.18% stable
Standard atomic weight Ar°(Ti)

Naturally occurring titanium (22Ti) is composed of five stable isotopes; Ti, Ti, Ti, Ti and Ti with Ti being the most abundant (73.8% natural abundance). Twenty-one radioisotopes have been characterized, with the most stable being Ti with a half-life of 60 years, Ti with a half-life of 184.8 minutes, Ti with a half-life of 5.76 minutes, and Ti with a half-life of 1.7 minutes. All of the remaining radioactive isotopes have half-lives that are less than 33 seconds, and the majority of these have half-lives that are less than half a second.

The isotopes of titanium range in atomic mass from 39.00 u (Ti) to 64.00 u (Ti). The primary decay mode for isotopes lighter than the stable isotopes (lighter than Ti) is β and the primary mode for the heavier ones (heavier than Ti) is β; their respective decay products are scandium isotopes and the primary products after are vanadium isotopes.

List of isotopes


Nuclide
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Natural abundance (mole fraction)
Excitation energy Normal proportion Range of variation
Ti 22 17 39.00268(22)# 28.5(9) ms β, p (93.7%) Ca 3/2+#
β (~6.3%) Sc
β, 2p (?%) K
Ti 22 18 39.990345(73) 52.4(3) ms β, p (95.8%) Ca 0+
β (4.2%) Sc
Ti 22 19 40.983148(30) 81.9(5) ms β, p (91.1%) Ca 3/2+
β (8.9%) Sc
Ti 22 20 41.97304937(29) 208.3(4) ms β Sc 0+
Ti 22 21 42.9685284(61) 509(5) ms β Sc 7/2−
Ti 313.0(10) keV 11.9(3) μs IT Ti (3/2+)
Ti 3066.4(10) keV 556(6) ns IT Ti (19/2−)
Ti 22 22 43.95968994(75) 59.1(3) y EC Sc 0+
Ti 22 23 44.95812076(90) 184.8(5) min β Sc 7/2−
Ti 36.53(15) keV 3.0(2) μs IT Ti 3/2−
Ti 22 24 45.952626356(97) Stable 0+ 0.0825(3)
Ti 22 25 46.951757491(85) Stable 5/2− 0.0744(2)
Ti 22 26 47.947940677(79) Stable 0+ 0.7372(3)
Ti 22 27 48.947864391(84) Stable 7/2− 0.0541(2)
Ti 22 28 49.944785.622(88) Stable 0+ 0.0518(2)
Ti 22 29 50.94660947(52) 5.76(1) min β V 3/2−
Ti 22 30 51.9468835(29) 1.7(1) min β V 0+
Ti 22 31 52.9496707(31) 32.7(9) s β V (3/2)−
Ti 22 32 53.950892(17) 2.1(10) s β V 0+
Ti 22 33 54.955091(31) 1.3(1) s β V (1/2)−
Ti 22 34 55.95768(11) 200(5) ms β V 0+
Ti 22 35 56.96307(22) 95(8) ms β V 5/2−#
Ti 22 36 57.96681(20) 55(6) ms β V 0+
Ti 22 37 58.97222(32)# 28.5(19) ms β V 5/2−#
Ti 108.5(5) keV 615(11) ns IT Ti 1/2−#
Ti 22 38 59.97628(26) 22.2(16) ms β V 0+
Ti 22 39 60.98243(32)# 15(4) ms β V 1/2−#
Ti 125.0(5) keV 200(28) ns IT Ti 5/2−#
Ti 700.1(7) keV 354(69) ns IT Ti 9/2+#
Ti 22 40 61.98690(43)# 9# ms
0+
Ti 22 41 62.99371(54)# 10# ms
1/2−#
Ti 22 42 63.99841(64)# 5# ms
0+
This table header & footer:
  1. Ti – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. Modes of decay:
    EC: Electron capture


    n: Neutron emission
    p: Proton emission
  6. Bold symbol as daughter – Daughter product is stable.
  7. ( ) spin value – Indicates spin with weak assignment arguments.

Titanium-44

Titanium-44 (Ti) is a radioactive isotope of titanium that undergoes electron capture to an excited state of scandium-44 with a half-life of 60 years, before the ground state of Sc and ultimately Ca are populated. Because titanium-44 can only undergo electron capture, its half-life increases with ionization and it becomes stable in its fully ionized state (that is, having a charge of +22).

Titanium-44 is produced in relative abundance in the alpha process in stellar nucleosynthesis and the early stages of supernova explosions. It is produced when calcium-40 fuses with an alpha particle (helium-4 nucleus) in a star's high-temperature environment; the resulting Ti nucleus can then fuse with another alpha particle to form chromium-48. The age of supernovae may be determined through measurements of gamma-ray emissions from titanium-44 and its abundance. It was observed in the Cassiopeia A supernova remnant and SN 1987A at a relatively high concentration, a consequence of delayed decay resulting from ionizing conditions.

References

  1. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. "Standard Atomic Weights: Titanium". CIAAW. 1993.
  3. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  4. ^ Barbalace, Kenneth L. (2006). "Periodic Table of Elements: Ti - Titanium". Retrieved 2006-12-26.
  5. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  6. ^ Motizuki, Y.; Kumagai, S. (2004). "Radioactivity of the key isotope Ti in SN 1987A". AIP Conference Proceedings. 704 (1): 369–374. arXiv:astro-ph/0312620. Bibcode:2004AIPC..704..369M. CiteSeerX 10.1.1.315.8412. doi:10.1063/1.1737130. S2CID 1700673.
  7. ^ Mochizuki, Y.; Takahashi, K.; Janka, H.-Th.; Hillebrandt, W.; Diehl, R. (2008). "Titanium-44: Its effective decay rate in young supernova remnants, and its abundance in Cas A". Astronomy and Astrophysics. 346 (3): 831–842. arXiv:astro-ph/9904378.
  8. Fryer, C.; Dimonte, G.; Ellinger, E.; Hungerford, A.; Kares, B.; Magkotsios, G.; Rockefeller, G.; Timmes, F.; Woodward, P.; Young, P. (2011). Nucleosynthesis in the Universe, Understanding Ti (PDF). ADTSC Science Highlights (Report). Los Alamos National Laboratory. pp. 42–43.
Isotopes of the chemical elements
Group 1 2   3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Period Hydrogen and
alkali metals
Alkaline
earth metals
Pnicto­gens Chal­co­gens Halo­gens Noble gases
Isotopes § ListH1 Isotopes § ListHe2
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1 asterisk Isotopes § ListLa57 Isotopes § ListCe58 Isotopes § ListPr59 Isotopes § ListNd60 Isotopes § ListPm61 Isotopes § ListSm62 Isotopes § ListEu63 Isotopes § ListGd64 Isotopes § ListTb65 Isotopes § ListDy66 Isotopes § ListHo67 Isotopes § ListEr68 Isotopes § ListTm69 Isotopes § ListYb70  
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