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Isotopes of tungsten

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Isotopes of tungsten (74W)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
W 0.120% 1.8×10 y α Hf
W synth 121.2 d ε Ta
W 26.5% stable
W 14.3% stable
W 30.6% stable
W synth 75.1 d β Re
W 28.4% stable
W synth 69.78 d β Re
Standard atomic weight Ar°(W)

Naturally occurring tungsten (74W) consists of five isotopes. Four are considered stable (W, W, W, and W) and one is slightly radioactive, W, with an extremely long half-life of 1.8 ± 0.2 exayears (10 years). On average, two alpha decays of W occur per gram of natural tungsten per year, so for most practical purposes, W can be considered stable. Theoretically, all five can decay into isotopes of element 72 (hafnium) by alpha emission, but only W has been observed to do so. The other naturally occurring isotopes have not been observed to decay (they are observationally stable), and lower bounds for their half-lives have been established:

W, t1/2 > 7.7×10 years
W, t1/2 > 4.1×10 years
W, t1/2 > 8.9×10 years
W, t1/2 > 8.2×10 years

Thirty-four artificial radioisotopes of tungsten have been characterized with mass numbers ranging from 156 to 194, the most stable of which are W with a half-life of 121.2 days, W with a half-life of 75.1 days, W with a half-life of 69.4 days and W with a half-life of 21.6 days. All of the remaining radioactive isotopes have half-lives of less than 24 hours, and most of these have half-lives that are less than 8 minutes. Tungsten also has 11 meta states with mass numbers of 158, 179, with 3, 180, with 2, 183, 185, 186, with 2, and 190, the most stable being W (t1/2 6.4 minutes).

List of isotopes


Nuclide
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Natural abundance (mole fraction)
Excitation energy Normal proportion Range of variation
W 74 82 157+57
−34 ms
β Ta 0+
W 74 83 275(40) ms β Ta (7/2−)
W 74 84 157.97456(54)# 1.37(17) ms α Hf 0+
W 1889(8) keV 143(19) μs α Hf 8+
W 74 85 158.97292(43)# 8.2(7) ms α (82%) Hf 7/2−#
β (18%) Ta
W 74 86 159.96848(22) 90(5) ms α (87%) Hf 0+
β (14%) Ta
W 74 87 160.96736(21)# 409(16) ms α (73%) Hf 7/2−#
β (23%) Ta
W 74 88 161.963497(19) 1.36(7) s β (53%) Ta 0+
α (47%) Hf
W 74 89 162.96252(6) 2.8(2) s β (59%) Ta 3/2−#
α (41%) Hf
W 74 90 163.958954(13) 6.3(2) s β (97.4%) Ta 0+
α (2.6%) Hf
W 74 91 164.958280(27) 5.1(5) s β (99.8%) Ta 3/2−#
α (.2%) Hf
W 74 92 165.955027(11) 19.2(6) s β (99.96%) Ta 0+
α (.035%) Hf
W 74 93 166.954816(21) 19.9(5) s β (>99.9%) Ta 3/2−#
α (<.1%) Hf
W 74 94 167.951808(17) 51(2) s β (99.99%) Ta 0+
α (.0319%) Hf
W 74 95 168.951779(17) 76(6) s β Ta (5/2−)
W 74 96 169.949228(16) 2.42(4) min β(99%) Ta 0+
α (1%) Hf
W 74 97 170.94945(3) 2.38(4) min β Ta (5/2−)
W 74 98 171.94729(3) 6.6(9) min β Ta 0+
W 74 99 172.94769(3) 7.6(2) min β Ta 5/2−
W 74 100 173.94608(3) 33.2(21) min β Ta 0+
W 74 101 174.94672(3) 35.2(6) min β Ta (1/2−)
W 74 102 175.94563(3) 2.5(1) h EC Ta 0+
W 74 103 176.94664(3) 132(2) min β Ta 1/2−
W 74 104 177.945876(16) 21.6(3) d EC Ta 0+
W 74 105 178.947070(17) 37.05(16) min β Ta (7/2)−
W 221.926(8) keV 6.40(7) min IT (99.72%) W (1/2)−
β (.28%) Ta
W 1631.90(8) keV 390(30) ns (21/2+)
W 3348.45(16) keV 750(80) ns (35/2−)
W 74 106 179.946704(4) 1.8(0.2)×10 y α Hf 0+ 0.0012(1)
W 1529.04(3) keV 5.47(9) ms IT W 8−
W 3264.56(21) keV 2.33(19) μs 14−
W 74 107 180.948197(5) 121.2(2) d EC Ta 9/2+
W 74 108 181.9482042(9) Observationally Stable 0+ 0.2650(16)
W 74 109 182.9502230(9) Observationally Stable 1/2− 0.1431(4)
W 309.493(3) keV 5.2(3) s IT W 11/2+
W 74 110 183.9509312(9) Observationally Stable 0+ 0.3064(2)
W 74 111 184.9534193(10) 75.1(3) d β Re 3/2−
W 197.43(5) keV 1.597(4) min IT W 11/2+
W 74 112 185.9543641(19) Observationally Stable 0+ 0.2843(19)
W 1517.2(6) keV 18(1) μs (7−)
W 3542.8(21) keV >3 ms (16+)
W 74 113 186.9571605(19) 23.72(6) h β Re 3/2−
W 74 114 187.958489(4) 69.78(5) d β Re 0+
W 74 115 188.96191(21) 11.6(3) min β Re (3/2−)
W 74 116 189.96318(18) 30.0(15) min β Re 0+
W 2381(5) keV <3.1 ms (10−)
W 74 117 190.96660(21)# 20# s
3/2−#
W 74 118 191.96817(64)# 10# s
0+
This table header & footer:
  1. W – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Bold half-life – nearly stable, half-life longer than age of universe.
  5. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  6. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
  7. Bold italics symbol as daughter – Daughter product is nearly stable.
  8. Bold symbol as daughter – Daughter product is stable.
  9. ( ) spin value – Indicates spin with weak assignment arguments.
  10. Primordial radionuclide
  11. Believed to undergo α decay to Hf with a half-life over 7.7×10 y
  12. Believed to undergo α decay to Hf with a half-life over 4.1×10 y
  13. Believed to undergo α decay to Hf with a half-life over 8.9×10 y
  14. Believed to undergo α decay to Hf or ββ decay to Os with a half-life over 8.2×10 y

References

  1. "Standard Atomic Weights: Tungsten". CIAAW. 1991.
  2. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  3. Briscoe, A. D.; Page, R. D.; Uusitalo, J.; et al. (2023). "Decay spectroscopy at the two-proton drip line: Radioactivity of the new nuclides Os and W". Physics Letters B. 47 (138310). doi:10.1016/j.physletb.2023.138310. hdl:10272/23933.
  4. Bianco, L.; Page, R. D.; Darby, I. G.; et al. (7 June 2010). "Discovery of W and Os" (PDF). Physics Letters B. 690 (1): 15–18. Bibcode:2010PhLB..690...15B. doi:10.1016/j.physletb.2010.04.056. ISSN 0370-2693. S2CID 117121162. Retrieved 11 June 2023.
Isotopes of the chemical elements
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