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Ytterbium(II) sulfide

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Ytterbium(II) sulfide
Names
Other names Ytterbium monosulfide, ytterbium(II) sulfide
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
InChI
  • InChI=1S/S.YbKey: QHGZBASAVJOMNS-UHFFFAOYSA-N
SMILES
  • .
Properties
Chemical formula SYb
Molar mass 205.11 g·mol
Appearance black crystals
Density 6.68 g/cm
Melting point 2,038 °C (3,700 °F; 2,311 K)
Structure
Crystal structure cubic
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Ytterbium(II) sulfide is a binary inorganic compound of ytterbium and sulfur with the chemical formula YbS.

Synthesis

Synthesis of ytterbium(II) sulfide can be via a reaction of pure substances in an inert atmosphere:

Yb + S → YbS

An alternative synthesis is by comproportionation of ytterbium(III) sulfide and ytterbium metal in vacuum at 1000–1100 °C:

Yb2S3 + Yb → 3YbS

Physical properties

Ytterbium(II) sulfide forms black crystals of cubic symmetry, space group Fm3m, cell parameter a = 0.5658 nm, Z = 4.

Ytterbium(II) sulfide demonstrates semiconductor behavior.

References

  1. O'Bannon, Loran (6 December 2012). Dictionary of Ceramic Science and Engineering. Springer Science & Business Media. p. 280. ISBN 978-1-4613-2655-7. Retrieved 4 April 2023.
  2. Derz, Friedrich W. (18 May 2020). H-Z. Walter de Gruyter GmbH & Co KG. p. 1971. ISBN 978-3-11-232209-3. Retrieved 4 April 2023.
  3. Kudryashov, M. A.; Logunov, A. A.; Mochalov, L. A. (2001). "Direct one-stage plasma-chemical synthesis of chalcogenide films doped with ytterbium". Journal of Physics: Conference Series. 1967: 012005. doi:10.1088/1742-6596/1967/1/012005.
  4. "mp-1820: YbS (Cubic, Fm-3m, 225)". Materials Project. Retrieved 4 April 2023.
  5. Chen, Yuqi; Li, Liang; Hirai, Shinji (1 April 2019). "Fabrication, sintering, heat capacity, magnetic and magnetroresistivity properties of ytterbium sulfides". Journal of Magnetism and Magnetic Materials. 476: 289–296. Bibcode:2019JMMM..476..289C. doi:10.1016/j.jmmm.2018.12.100. ISSN 0304-8853. S2CID 127540609. Retrieved 4 April 2023.
Ytterbium compounds
Yb(II)
Yb(III)
Other
Sulfides (S)
H2S He
Li2S BeS B2S3
+BO3
CS2
COS
(NH4)SH O F Ne
Na2S MgS Al2S3 SiS
SiS2
-Si
PxSy
-P
-S
2
Cl Ar
K2S CaS ScS
Sc2S3
TiS
TiS2
Ti2S3
TiS3
VS
VS2
V2S3
CrS
Cr2S3
MnS
MnS2
FeS
Fe3S4
CoxSy NixSy Cu2S
CuS
ZnS GaS
Ga2S3
GeS
GeS2
-Ge
As2S3
As4S3
-As
SeS2
+Se
Br Kr
Rb2S SrS Y2S3 ZrS2 NbS2 MoS2
MoS3
TcS2
Tc2S7
Ru Rh2S3 PdS Ag2S CdS In2S3 SnS
SnS2
-Sn
Sb2S3
Sb2S5
-Sb
TeS2 I Xe
Cs2S BaS * LuS
Lu2S3
HfS2 TaS2 WS2
WS3
ReS2
Re2S7
OsS
4
Ir2S3
IrS2
PtS
PtS2
Au2S
Au2S3
HgS Tl2S PbS
PbS2
Bi2S3 PoS At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaS
La2S3
CeS
Ce2S3
PrS
Pr2S3
NdS
Nd2S3
PmS
Pm2S3
SmS
Sm2S3
EuS
Eu2S3
GdS
Gd2S3
TbS
Tb2S3
DyS
Dy2S3
HoS
Ho2S3
ErS
Er2S3
TmS
Tm2S3
YbS
Yb2S3
** Ac2S3 ThS2 Pa US
US2
Np Pu Am Cm Bk Cf Es Fm Md No
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