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Boron phosphate

Names
IUPAC name Boron phosphate
Systematic IUPAC name 2,4,5-trioxa-1λ-phospha-3-borabicyclopentane 1-oxide
Identifiers
CAS Number	13308-51-5
3D model (JSmol)	Interactive image
ChemSpider	75189
ECHA InfoCard	100.033.020
PubChem CID	83329
CompTox Dashboard (EPA)	DTXSID10872553
InChI InChI=1S/B.H3O4P/c;1-5(2,3)4/h;(H3,1,2,3,4)/q+3;/p-3Key: YZYDPPZYDIRSJT-UHFFFAOYSA-K InChI=1/B.H3O4P/c;1-5(2,3)4/h;(H3,1,2,3,4)/q+3;/p-3Key: YZYDPPZYDIRSJT-DFZHHIFOAS
SMILES B12OP(=O)(O1)O2
Properties
Chemical formula	BPO4
Molar mass	105.78 g/mol
Density	2.52 g/cm
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H302
Precautionary statements	P264, P270, P301+P312, P330, P501
NFPA 704 (fire diamond)	2 0 0
Safety data sheet (SDS)	External SDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references

Boron phosphate is an inorganic compound with the chemical formula BPO₄. The simplest way of producing it is the reaction of phosphoric acid and boric acid. It is a white infusible solid that evaporates above 1450 °C.

Synthesis

Boron phosphate is synthesized from phosphoric acid and boric acid at a temperature range from 80 °C to 1200 °C. The relatively cold treatment produces a white amorphous powder, which is converted to a microcrystalline product when heated at about 1000 °C for 2 hours.

The main reaction of the process is:

H₃BO₃ + H₃PO₄ → BPO₄ + 3 H₂O

New ways of synthesizing the compound have also been reported, such as hydrothermal and microwave synthesis.

Due to the particular industrial interest of boron phosphate, other methods are used as well:

• Phosphoric acid and triethyl borate
• Triethyl phosphate and boron trichloride
• Diammonium phosphate acid and borax heated to 1000 °C
• Boric acid and phosphorus pentoxide (hydrothermal)

Structure

If obtained at pressure, the ordinary structure is isomorphous with the β-cristobalite, while subjecting it to high pressure is obtained a compound isomorphic with α-quartz. The structure of AlPO₄, berlinite, is isomorphous with α-quartz.

Applications

It is used as a catalyst for dehydration and other reactions in organic synthesis. Also, it serves as a source of phosphates for exchange reactions in the solid state to obtain metal phosphates.

References

1. pubchem.ncbi.nlm.nih.gov/compound/83329#section=IUPAC-Name&fullscreen=true
2. Boron phosphate datasheets.scbt.com
3. ^ Corbridge DEC 2013, Phosphorus: Chemistry, Biochemistry and Technology, 6th ed., CRC Press, Boca Raton, Florida, ISBN 978-1-4398-4088-7
4. Mylius, F.; Meusser, A. (1904). "Ueber die Bestimmung der Borsäure als Phosphat". Berichte der Deutschen Chemischen Gesellschaft. 37: 397–401. doi:10.1002/cber.19040370171.
5. ^ Baykal, A; Kizilyalli, M; Toprak, Muhammet S. & Kniep, R (2001). "Hydrothermal and microwave synthesis of boron phosphate, BPO₄". Turkish Journal of Chemistry. 25 (4): 425–432.
6. MacKenzie, J. D.; Roth, W. L.; Wentorf, R. H. (1959). "New high pressure modifications of BPO₄ and BAsO₄". Acta Crystallographica. 12 (1): 79. Bibcode:1959AcCry..12...79M. doi:10.1107/S0365110X5900024X.
7. Moffat, J. B.; Goltz, H. L. (1965). "Surface Chemistry and Catalytic Properties of Boron Phosphate: 1. Surface Area and Acidity". Canadian Journal of Chemistry. 43 (6): 1680. doi:10.1139/v65-222.

• Boron compounds
• Phosphates