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Isotopes of gadolinium

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Isotopes of gadolinium (64Gd)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
Gd synth 86.9 y α Sm
Gd synth 1.79×10 y α Sm
Gd 0.2% 1.08×10 y α Sm
Gd synth 240.6 d ε Eu
Gd 2.18% stable
Gd 14.8% stable
Gd 20.5% stable
Gd 15.7% stable
Gd 24.8% stable
Gd 21.9% stable
Standard atomic weight Ar°(Gd)

Naturally occurring gadolinium (64Gd) is composed of 6 stable isotopes, Gd, Gd, Gd, Gd, Gd and Gd, and 1 radioisotope, Gd, with Gd being the most abundant (24.84% natural abundance). The predicted double beta decay of Gd has never been observed; only a lower limit on its half-life of more than 1.3×10 years has been set experimentally.

Thirty-three radioisotopes have been characterized, with the most stable being alpha-decaying Gd (naturally occurring) with a half-life of 1.08×10 years, and Gd with a half-life of 1.79×10 years. All of the remaining radioactive isotopes have half-lives less than 100 years, the majority of these having half-lives less than 24.6 seconds. Gadolinium isotopes have 10 metastable isomers, with the most stable being Gd (t1/2 = 110 seconds), Gd (t1/2 = 85 seconds) and Gd (t1/2 = 24.5 seconds).

The primary decay mode at atomic weights lower than the most abundant stable isotope, Gd, is electron capture, and the primary mode at higher atomic weights is beta decay. The primary decay products for isotopes lighter than Gd are isotopes of europium and the primary products of heavier isotopes are isotopes of terbium.

List of isotopes


Nuclide
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Natural abundance (mole fraction)
Excitation energy Normal proportion Range of variation
Gd 64 71 134.95250(43)# 1.1(2) s β (98%) Eu (5/2+)
β, p (98%) Sm
Gd 64 72 135.94730(32)# 1# s β? Eu 0+
β, p? Sm
Gd 64 73 136.94502(32)# 2.2(2) s β Eu (7/2)+#
β, p? Sm
Gd 64 74 137.94025(22)# 4.7(9) s β Eu 0+
Gd 2232.6(11) keV 6.2(0.2) μs IT Gd (8−)
Gd 64 75 138.93813(21)# 5.7(3) s β Eu 9/2−#
β, p? Sm
Gd 250(150)# keV 4.8(9) s β Eu 1/2+#
β, p? Sm
Gd 64 76 139.933674(30) 15.8(4) s β (67(8)%) Eu 0+
EC (33(8)%)
Gd 64 77 140.932126(21) 14(4) s β (99.97%) Eu (1/2+)
β, p (0.03%) Sm
Gd 377.76(9) keV 24.5(5) s β (89%) Eu (11/2−)
IT (11%) Gd
Gd 64 78 141.928116(30) 70.2(6) s EC (52(5)%) Eu 0+
β (48(5)%)
Gd 64 79 142.92675(22) 39(2) s β Eu 1/2+
β, p? Sm
β, α? Pm
Gd 152.6(5) keV 110.0(14) s β Eu 11/2−
β, p? Sm
β, α? Pm
Gd 64 80 143.922963(30) 4.47(6) min β Eu 0+
Gd 3433.1(5) keV 145(30) ns IT Gd (10+)
Gd 64 81 144.921710(21) 23.0(4) min β Eu 1/2+
Gd 749.1(2) keV 85(3) s IT (94.3%) Gd 11/2−
β (5.7%) Eu
Gd 64 82 145.9183185(44) 48.27(10) d EC Eu 0+
Gd 64 83 146.9191010(20) 38.06(12) h β Eu 7/2−
Gd 8587.8(5) keV 510(20) ns IT Gd 49/2+
Gd 64 84 147.9181214(16) 86.9(39) y α Sm 0+
Gd 64 85 148.9193477(36) 9.28(10) d β Eu 7/2−
α (4.3×10%) Sm
Gd 64 86 149.9186639(65) 1.79(8)×10 y α Sm 0+
Gd 64 87 150.9203549(32) 123.9(10) d EC Eu 7/2−
α (1.1×10%) Sm
Gd 64 88 151.9197984(11) 1.08(8)×10 y α Sm 0+ 0.0020(1)
Gd 64 89 152.9217569(11) 240.6(7) d EC Eu 3/2−
Gd 95.1737(8) keV 3.5(4) μs IT Gd 9/2+
Gd 171.188(4) keV 76.0(14) μs IT Gd (11/2−)
Gd 64 90 153.9208730(11) Observationally Stable 0+ 0.0218(2)
Gd 64 91 154.9226294(11) Observationally Stable 3/2− 0.1480(9)
Gd 121.10(19) keV 31.97(27) ms IT Gd 11/2−
Gd 64 92 155.9221301(11) Stable 0+ 0.2047(3)
Gd 2137.60(5) keV 1.3(1) μs IT Gd 7-
Gd 64 93 156.9239674(10) Stable 3/2− 0.1565(4)
Gd 63.916(5) keV 460(40) ns IT Gd 5/2+
Gd 426.539(23) keV 18.5(23) μs IT Gd 11/2−
Gd 64 94 157.9241112(10) Stable 0+ 0.2484(8)
Gd 64 95 158.9263958(11) 18.479(4) h β Tb 3/2−
Gd 64 96 159.9270612(12) Observationally Stable 0+ 0.2186(3)
Gd 64 97 160.9296763(16) 3.646(3) min β Tb 5/2−
Gd 64 98 161.9309918(43) 8.4(2) min β Tb 0+
Gd 64 99 162.93409664(86) 68(3) s β Tb 7/2+
Gd 138.22(20) keV 23.5(10) s IT? Gd 1/2−
β Tb
Gd 64 100 163.9359162(11) 45(3) s β Tb 0+
Gd 1095.8(4) keV 589(18) ns IT Gd (4−)
Gd 64 101 164.9393171(14) 11.6(10) s β Tb 1/2−#
Gd 64 102 165.9416304(17) 5.1(8) s β Tb 0+
Gd 1601.5(11) keV 950(60) ns IT Gd (6−)
Gd 64 103 166.9454900(56) 4.2(3) s β Tb 5/2−#
Gd 64 104 167.94831(32)# 3.03(16) s β Tb 0+
Gd 64 105 168.95288(43)# 750(210) ms β Tb 7/2−#
β, n? (<0.7%) Tb
Gd 64 106 169.95615(54)# 675+94
−75 ms
β Tb 0+
β, n? (<3%) Tb
Gd 64 107 170.96113(54)# 392+145
−136 ms
β Tb 9/2+#
β, n? (<10%) Tb
Gd 64 108 171.96461(32)# 163+113
−99 ms
β Tb 0+#
β, n? (<50%) Tb
This table header & footer:
  1. Gd – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Bold half-life – nearly stable, half-life longer than age of universe.
  5. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  6. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
  7. Bold italics symbol as daughter – Daughter product is nearly stable.
  8. Bold symbol as daughter – Daughter product is stable.
  9. ( ) spin value – Indicates spin with weak assignment arguments.
  10. Order of ground state and isomer is uncertain.
  11. Theorized to also undergo ββ decay to Sm
  12. Theorized to also undergo ββ decay to Sm
  13. primordial radionuclide
  14. Theorized to also undergo ββ decay to Sm
  15. Believed to undergo α decay to Sm
  16. ^ Fission product
  17. Believed to undergo α decay to Sm
  18. Believed to undergo ββ decay to Dy with a half-life over 3.1×10 years

Gadolinium-148

With a half-life of 86.9±3.9 year via alpha decay alone, gadolinium-148 would be ideal for radioisotope thermoelectric generators. However, gadolinium-148 cannot be economically synthesized in sufficient quantities to power a RTG.

Gadolinium-153

Gadolinium-153 has a half-life of 240.4±10 d and emits gamma radiation with strong peaks at 41 keV and 102 keV. It is used as a gamma ray source for X-ray absorptiometry and fluorescence, for bone density gauges for osteoporosis screening, and for radiometric profiling in the Lixiscope portable x-ray imaging system, also known as the Lixi Profiler. In nuclear medicine, it serves to calibrate the equipment needed like single-photon emission computed tomography systems (SPECT) to make x-rays. It ensures that the machines work correctly to produce images of radioisotope distribution inside the patient. This isotope is produced in a nuclear reactor from europium or enriched gadolinium. It can also detect the loss of calcium in the hip and back bones, allowing the ability to diagnose osteoporosis.

References

  1. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. ^ Chiera, Nadine M.; Dressler, Rugard; Sprung, Peter; Talip, Zeynep; Schumann, Dorothea (2023). "Determination of the half-life of gadolinium-148". Applied Radiation and Isotopes. 194. Elsevier BV: 110708. doi:10.1016/j.apradiso.2023.110708. ISSN 0969-8043.
  3. "Standard Atomic Weights: Gadolinium". CIAAW. 2024.
  4. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  5. F. A. Danevich; et al. (2001). "Quest for double beta decay of Gd and Ce isotopes". Nuclear Physics A. 694 (1–2): 375–391. arXiv:nucl-ex/0011020. Bibcode:2001NuPhA.694..375D. doi:10.1016/S0375-9474(01)00983-6. S2CID 11874988.
  6. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  7. ^ Kiss, G. G.; Vitéz-Sveiczer, A.; Saito, Y.; et al. (2022). "Measuring the β-decay properties of neutron-rich exotic Pm, Sm, Eu, and Gd isotopes to constrain the nucleosynthesis yields in the rare-earth region". The Astrophysical Journal. 936 (107): 107. Bibcode:2022ApJ...936..107K. doi:10.3847/1538-4357/ac80fc. hdl:2117/375253.
  8. Council, National Research; Sciences, Division on Engineering Physical; Board, Aeronautics Space Engineering; Board, Space Studies; Committee, Radioisotope Power Systems (2009). Radioisotope Power Systems: An Imperative for Maintaining U.S. Leadership in Space Exploration. CiteSeerX 10.1.1.367.4042. doi:10.17226/12653. ISBN 978-0-309-13857-4.
  9. "PNNL: Isotope Sciences Program – Gadolinium-153". pnl.gov. Archived from the original on 2009-05-27.
  10. "Gadolinium". BCIT Chemistry Resource Center. British Columbia Institute of Technology. Archived from the original on 23 August 2011. Retrieved 30 March 2011.
Isotopes of the chemical elements
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