Misplaced Pages

Scandium nitride

Article snapshot taken from Wikipedia with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
Scandium nitride
Names
IUPAC name Scandium nitride
Other names Azanylidynescandium
Nitridoscandium
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.042.938 Edit this at Wikidata
EC Number
  • 247-247-2
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/N.ScKey: CUOITRGULIVMPC-UHFFFAOYSA-N
SMILES
  • N#
Properties
Chemical formula ScN
Molar mass 58.963
Density 4.4 g/cm
Melting point 2,600 °C (4,710 °F; 2,870 K)
Hazards
GHS labelling:
Pictograms GHS07: Exclamation mark
Signal word Danger
Hazard statements H228
Related compounds
Other anions Scandium phosphide
Scandium arsenide
Scandium antimonide
Scandium bismuthide
Other cations Yttrium nitride
Lutetium nitride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Scandium nitride (ScN) is a binary III-V indirect bandgap semiconductor. It is composed of the scandium cation and the nitride anion. It forms crystals that can be grown on tungsten foil through sublimation and recondensation. It has a rock-salt crystal structure with lattice constant of 0.451 nanometer, an indirect bandgap of 0.9 eV and direct bandgap of 2 to 2.4 eV. These crystals can be synthesized by dissolving nitrogen gas with indium-scandium melts, magnetron sputtering, MBE, HVPE and other deposition methods. Scandium nitride is also an effective gate for semiconductors on a silicon dioxide (SiO2) or hafnium dioxide (HfO2) substrate.


References

  1. ^ Gu, Zheng; Edgar, J H; Pomeroy, J; Kuball, M; Coffey, D W (August 2004). "Crystal Growth and Properties of Scandium Nitride". Journal of Materials Science: Materials in Electronics. 15 (8): 555–559. doi:10.1023/B:JMSE.0000032591.54107.2c. S2CID 98462001.
  2. ^ Biswas, Bidesh; Saha, Bivas (2019-02-14). "Development of semiconducting ScN". Physical Review Materials. 3 (2): 020301. Bibcode:2019PhRvM...3b0301B. doi:10.1103/physrevmaterials.3.020301. ISSN 2475-9953. S2CID 139544303.
  3. Zhang, Guodong; Kawamura, Fumio; Oshima, Yuichi; Villora, Encarnacion; Shimamura, Kiyoshi (4 August 2016). "Synthesis of Scandium Nitride Crystals from Indium–Scandium Melts". International Journal of Applied Ceramic Technology. 13 (6): 1134–1138. doi:10.1111/ijac.12576.
  4. Yang, Hyundoek; Heo, Sungho; Lee, Dongkyu; Choi, Sangmoo; Hwang, Hyunsang (13 January 2006). "Effective Work Function of Scandium Nitride Gate Electrodes on SiO2 and HfO2". Japanese Journal of Applied Physics. 45 (2): L83–L85. Bibcode:2006JaJAP..45L..83Y. doi:10.1143/JJAP.45.L83. S2CID 121206924.
Scandium compounds
Salts and covalent derivatives of the nitride ion
NH3
N2H4
+H
HN
H2N
He(N2)11
Li3N
LiN3
Be3N2
Be(N3)2
BN
-B
C2N2
β-C3N4
g-C3N4
CxNy
N2 NxOy
+O
N3F
N2F2
N2F4
NF3
+F
Ne
Na3N
NaN3
Mg3N2
Mg(N3)2
AlN Si3N4
-Si
PN
P3N5
-P
SxNy
SN
S2N2
S4N4
SN2H2
NCl3
ClN3
+Cl
Ar
K3N
KN3
Ca3N2
Ca(N3)2
ScN TiN
Ti3N4
VN CrN
Cr2N
MnxNy FexNy Co3N Ni3N Cu3N Zn3N2 GaN Ge3N4
-Ge
AsN
+As
Se4N4 Br3N
BrN3
+Br
Kr
RbN3 Sr3N2
Sr(N3)2
YN ZrN NbN β-Mo2N Tc Ru Rh PdN Ag3N Cd3N2 InN Sn SbN Te4N4? I3N
IN3
+I
Xe
CsN3 Ba3N2
Ba(N3)2
* LuN HfN
Hf3N4
TaN WN RexNy Os Ir Pt Au Hg3N2 Tl3N (PbNH) BiN Po At Rn
Fr Ra3N2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaN CeN PrN NdN PmN SmN EuN GdN TbN DyN HoN ErN TmN YbN
** Ac ThxNy PaN UxNy NpN PuN AmN CmN BkN Cf Es Fm Md No


Stub icon

This inorganic compound–related article is a stub. You can help Misplaced Pages by expanding it.

Categories: