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Isotopes of selenium

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Isotopes of selenium (34Se)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
Se synth 8.4 d ε As
γ
Se 0.860% stable
Se synth 119.8 d ε As
γ
Se 9.23% stable
Se 7.60% stable
Se 23.7% stable
Se trace 3.27×10 y β Br
Se 49.8% stable
Se 8.82% 8.76×10 y ββ Kr
Standard atomic weight Ar°(Se)

Selenium (34Se) has six natural isotopes that occur in significant quantities, along with the trace isotope Se, which occurs in minute quantities in uranium ores. Five of these isotopes are stable: Se, Se, Se, Se, and Se. The last three also occur as fission products, along with Se, which has a half-life of 327,000 years, and Se, which has a very long half-life (~10 years, decaying via double beta decay to Kr) and for practical purposes can be considered to be stable. There are 23 other unstable isotopes that have been characterized, the longest-lived being Se with a half-life 327,000 years, Se with a half-life of 120 days, and Se with a half-life of 8.40 days. Of the other isotopes, Se has the longest half-life, 7.15 hours; most others have half-lives not exceeding 38 seconds.

List of isotopes

Nuclide
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Natural abundance (mole fraction)
Excitation energy Normal proportion Range of variation
Se 34 29 62.98191(54)# 13.2(39) ms β, p (89%) Ge 3/2−#
β (11%) As
2p? (<0.5%) Ge
Se 34 30 63.97117(54)# 22.6(2) ms β? As 0+
β, p? Ge
Se 34 31 64.96455(32)# 34.2(7) ms β, p (87%) Ge 3/2−#
β (13%) As
Se 34 32 65.95528(22)# 54(4) ms β As 0+
β, p? Ge
Se 34 33 66.949994(72) 133(4) ms β (99.5%) As 5/2−#
β, p (0.5%) Ge
Se 34 34 67.94182524(53) 35.5(7) s β As 0+
Se 34 35 68.9394148(16) 27.4(2) s β (99.95%) As 1/2−
β, p (.052%) Ge
Se 38.85(22) keV 2.0(2) μs IT Se 5/2−
Se 574.0(4) keV 955(16) ns IT Se 9/2+
Se 34 36 69.9335155(17) 41.1(3) min β As 0+
Se 34 37 70.9322094(30) 4.74(5) min β As (5/2−)
Se 48.79(5) keV 5.6(7) μs IT Se (1/2−)
Se 260.48(10) keV 19.0(5) μs IT Se (9/2+)
Se 34 38 71.9271405(21) 8.40(8) d EC As 0+
Se 34 39 72.9267549(80) 7.15(9) h β As 9/2+
Se 25.71(4) keV 39.8(17) min IT (72.6%) Se 3/2−
β (27.4%) As
Se 34 40 73.922475933(15) Observationally Stable 0+ 0.0086(3)
Se 34 41 74.922522870(78) 119.78(3) d EC As 5/2+
Se 34 42 75.919213702(17) Stable 0+ 0.0923(7)
Se 34 43 76.919914150(67) Stable 1/2− 0.0760(7)
Se 161.9223(10) keV 17.36(5) s IT Se 7/2+
Se 34 44 77.91730924(19) Stable 0+ 0.2369 (22)
Se 34 45 78.91849925(24) 3.27(28)×10 y β Br 7/2+
Se 95.77(3) keV 3.900(18) min IT (99.94%) Se 1/2−
β (0.056%) Br
Se 34 46 79.9165218(10) Observationally Stable 0+ 0.4980(36)
Se 34 47 80.9179930(10) 18.45(12) min β Br 1/2−
Se 103.00(6) keV 57.28(2) min IT (99.95%) Se 7/2+
β (.051%) Br
Se 34 48 81.91669953(50) 8.76(15)×10 y ββ Kr 0+ 0.0882(15)
Se 34 49 82.9191186(33) 22.25(4) min β Br 9/2+
Se 228.92(7) keV 70.1(4) s β Br 1/2−
Se 34 50 83.9184668(21) 3.26(10) min β Br 0+
Se 34 51 84.9222608(28) 32.9(3) s β Br (5/2)+
Se 34 52 85.9243117(27) 14.3(3) s β Br 0+
β, n? Br
Se 34 53 86.9286886(24) 5.50(6) s β (99.50%) Br (3/2+)
β, n (0.60%) Br
Se 34 54 87.9314175(36) 1.53(6) s β (99.01%) Br 0+
β, n (0.99%) Br
Se 34 55 88.9366691(40) 430(50) ms β (92.2%) Br 5/2+#
β, n (7.8%) Br
Se 34 56 89.94010(35) 210(80) ms β Br 0+
β, n? Br
Se 34 57 90.94570(47) 270(50) ms β (79%) Br 1/2+#
β, n (21%) Br
β, 2n? Br
Se 34 58 91.94984(43)# 90# ms β? Br 0+
β, n? Br
β, 2n? Br
Se 3072(2) keV 15.7(7) μs IT Se (9−)
Se 34 59 92.95614(43)# 130# ms β? Br 1/2+#
β, n? Br
β, 2n? Br
Se 678.2(7) keV 420(100) ns IT Se
Se 34 60 93.96049(54)# 50# ms β? Br 0+
β, n? Br
β, 2n? Br
Se 2430.0(6) keV 680(50) ns IT Se (7−)
Se 34 61 94.96730(54)# 70# ms β? Br 3/2+#
β, n? Br
β, 2n? Br
Se 34 62
Se 34 63
This table header & footer:
  1. Se – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Bold half-life – nearly stable, half-life longer than age of universe.
  5. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  6. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  7. Bold symbol as daughter – Daughter product is stable.
  8. ( ) spin value – Indicates spin with weak assignment arguments.
  9. Believed to decay by ββ to Ge with a half-life over 2.3×10 y.
  10. Long-lived fission product
  11. Believed to decay by ββ to Kr
  12. Primordial radionuclide

Use of radioisotopes

The isotope selenium-75 has radiopharmaceutical uses. For example, it is used in high-dose-rate endorectal brachytherapy, as an alternative to iridium-192.

In paleobiogeochemistry, the ratio in amount of selenium-82 to selenium-76 (i.e, the value of δSe) can be used to track down the redox conditions on Earth during the Neoproterozoic era in order to gain a deeper understanding of the rapid oxygenation that trigger the emergence of complex organisms.

References

  1. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. "Standard Atomic Weights: Selenium". CIAAW. 2013.
  3. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  4. The half-life of Se Archived September 27, 2011, at the Wayback Machine
  5. Jorg, Gerhard; Buhnemann, Rolf; Hollas, Simon; Kivel, Niko; Kossert, Karsten; Van Winckel, Stefaan; Gostomski, Christoph Lierse v. (2010). "Preparation of radiochemically pure Se and highly precise determination of its half-life". Applied Radiation and Isotopes. 68 (12): 2339–51. doi:10.1016/j.apradiso.2010.05.006. PMID 20627600.
  6. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  7. ^ Shimizu, Y.; Kubo, T.; Sumikama, T.; Fukuda, N.; Takeda, H.; Suzuki, H.; Ahn, D. S.; Inabe, N.; Kusaka, K.; Ohtake, M.; Yanagisawa, Y.; Yoshida, K.; Ichikawa, Y.; Isobe, T.; Otsu, H.; Sato, H.; Sonoda, T.; Murai, D.; Iwasa, N.; Imai, N.; Hirayama, Y.; Jeong, S. C.; Kimura, S.; Miyatake, H.; Mukai, M.; Kim, D. G.; Kim, E.; Yagi, A. (8 April 2024). "Production of new neutron-rich isotopes near the N = 60 isotones Ge 92 and As 93 by in-flight fission of a 345 MeV/nucleon U 238 beam". Physical Review C. 109 (4). doi:10.1103/PhysRevC.109.044313.
  8. Shoemaker T; Vuong T; Glickman H; Kaifi S; Famulari G; Enger SA (2019). "Dosimetric Considerations for Ytterbium-169, Selenium-75, and Iridium-192 Radioisotopes in High-Dose-Rate Endorectal Brachytherapy". Int J Radiat Oncol Biol Phys. 105 (4): 875–883. doi:10.1016/j.ijrobp.2019.07.003. PMID 31330175. S2CID 198170324.
  9. Pogge von Strandmann, Philip A. E.; Stüeken, Eva E.; Elliott, Tim; Poulton, Simon W.; Dehler, Carol M.; Canfield, Don E.; Catling, David C. (2015-12-18). "Selenium isotope evidence for progressive oxidation of the Neoproterozoic biosphere". Nature Communications. 6 (1): 10157. doi:10.1038/ncomms10157. ISSN 2041-1723. PMC 4703861. PMID 26679529.
  10. Stüeken, Eva E. "Selenium isotopes as a biogeochemical proxy in deep time" (PDF). core.ac.uk.
Isotopes of the chemical elements
Group 1 2   3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Period Hydrogen and
alkali metals
Alkaline
earth metals
Pnicto­gens Chal­co­gens Halo­gens Noble gases
Isotopes § ListH1 Isotopes § ListHe2
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Isotopes § ListNa11 Isotopes § ListMg12 Isotopes § ListAl13 Isotopes § ListSi14 Isotopes § ListP15 Isotopes § ListS16 Isotopes § ListCl17 Isotopes § ListAr18
Isotopes § ListK19 Isotopes § ListCa20 Isotopes § ListSc21 Isotopes § ListTi22 Isotopes § ListV23 Isotopes § ListCr24 Isotopes § ListMn25 Isotopes § ListFe26 Isotopes § ListCo27 Isotopes § ListNi28 Isotopes § ListCu29 Isotopes § ListZn30 Isotopes § ListGa31 Isotopes § ListGe32 Isotopes § ListAs33 Isotopes § ListSe34 Isotopes § ListBr35 Isotopes § ListKr36
Isotopes § ListRb37 Isotopes § ListSr38 Isotopes § ListY39 Isotopes § ListZr40 Isotopes § ListNb41 Isotopes § ListMo42 Isotopes § ListTc43 Isotopes § ListRu44 Isotopes § ListRh45 Isotopes § ListPd46 Isotopes § ListAg47 Isotopes § ListCd48 Isotopes § ListIn49 Isotopes § ListSn50 Isotopes § ListSb51 Isotopes § ListTe52 Isotopes § ListI53 Isotopes § ListXe54
Isotopes § ListCs55 Isotopes § ListBa56 1 asterisk Isotopes § ListLu71 Isotopes § ListHf72 Isotopes § ListTa73 Isotopes § ListW74 Isotopes § ListRe75 Isotopes § ListOs76 Isotopes § ListIr77 Isotopes § ListPt78 Isotopes § ListAu79 Isotopes § ListHg80 Isotopes § ListTl81 Isotopes § ListPb82 Isotopes § ListBi83 Isotopes § ListPo84 Isotopes § ListAt85 Isotopes § ListRn86
Isotopes § ListFr87 Isotopes § ListRa88 1 asterisk Isotopes § ListLr103 Isotopes § ListRf104 Isotopes § ListDb105 Isotopes § ListSg106 Isotopes § ListBh107 Isotopes § ListHs108 Isotopes § ListMt109 Isotopes § ListDs110 Isotopes § ListRg111 Isotopes § ListCn112 Isotopes § ListNh113 Isotopes § ListFl114 Isotopes § ListMc115 Isotopes § ListLv116 Isotopes § ListTs117 Isotopes § ListOg118
Isotopes § ListUue119 Isotopes § ListUbn120
1 asterisk Isotopes § ListLa57 Isotopes § ListCe58 Isotopes § ListPr59 Isotopes § ListNd60 Isotopes § ListPm61 Isotopes § ListSm62 Isotopes § ListEu63 Isotopes § ListGd64 Isotopes § ListTb65 Isotopes § ListDy66 Isotopes § ListHo67 Isotopes § ListEr68 Isotopes § ListTm69 Isotopes § ListYb70  
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