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Actinium(III) phosphate

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Actinium(III) phosphate
Names
Other names Actinium monophosphate
Identifiers
3D model (JSmol)
InChI
  • InChI=1S/Ac.H3O4P/c;1-5(2,3)4/h;(H3,1,2,3,4)/q+3;/p-3Key: PVLPTTWSKILMQQ-UHFFFAOYSA-K
SMILES
  • P(=O)().
Properties
Chemical formula AcPO4
Molar mass 321.9714 g/mol
Appearance White solid
Density 5.48 g/cm
Structure
Crystal structure hexagonal
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Actinium(III) phosphate is a white-colored chemical compound of the radioactive element actinium. This compound was created by reacting actinium(III) chloride with monosodium phosphate in aqueous hydrochloric acid. This resulted in the hemihydrate AcPO4·1/2H2O, whose structure was confirmed by x-ray diffraction to match that of lanthanum phosphate. To become anhydrous, it was heated to 700 °C, which resulted in a solid that was black (presumably due to the presence of impurities), and whose specific X-ray structure did not match that of other known correspond to other actinide phosphates.

References

  1. ^ the University of Michigan (1948). The Preparation of Actinium Compounds. U.S. Atomic Energy Commission, Technical Information Division. p. 4. Retrieved 16 April 2021.
  2. Zachariasen, W. H. (1948). "Crystal chemical studies of the 5f-series of elements. I. New structure types". Acta Crystallographica. 1 (5): 265–268. Bibcode:1948AcCry...1..265Z. doi:10.1107/S0365110X48000703.
Actinium compounds
Phosphates
H3PO4

He
Li3PO4 Be BPO4
+BO3
C (NH4)3PO4
(NH4)2HPO4
NH4H2PO4
-N
O +F Ne
Na3PO4
Na2HPO4
NaH2PO4
Mg3(PO4)2 AlPO4 Si P +SO4
-S
Cl Ar
K3PO4
K2HPO4
KH2PO4
Ca3(PO4)2 ScPO4 Ti VPO4 CrPO4 Mn3(PO4)2
MnPO4
Fe3(PO4)2
FePO4
Co3(PO4)2 Ni3(PO4)2 Cu3(PO4)2 Zn3(PO4)2 GaPO4 Ge As -Se Br Kr
Rb3PO4 Sr3(PO4)2 YPO4 Zr3(PO4)4 Nb Mo Tc Ru Rh Pd Ag3PO4 Cd3(PO4)2 InPO4 Sn SbPO4
-SbO4
Te I Xe
Cs3PO4 Ba3(PO4)2 * LuPO4 Hf Ta W Re Os Ir Pt AuPO4 Hg Tl3PO4 Pb3(PO4)2 BiPO4 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaPO4 CePO4 PrPO4 NdPO4 PmPO4 SmPO4 EuPO4 GdPO4 TbPO4 DyPO4 HoPO4 ErPO4 TmPO4 YbPO4
** AcPO4 Th3(PO4)4 Pa U(PO4)2 Np PuPO4 AmPO4 CmPO4 Bk Cf Es Fm Md No
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