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Dipotassium phosphate

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Dipotassium phosphate
Names
IUPAC name Potassium hydrogen phosphate
Other names Potassium monohydrogen phosphate
Phosphoric acid dipotassium salt
Potassium phosphate dibasic
Identifiers
CAS Number
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.028.940 Edit this at Wikidata
EC Number
  • 231-834-5
E number E340(ii) (antioxidants, ...)
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/2K.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q2*+1;/p-2Key: ZPWVASYFFYYZEW-UHFFFAOYSA-L
  • InChI=1/2K.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q2*+1;/p-2Key: ZPWVASYFFYYZEW-NUQVWONBAH
SMILES
  • ..P()(=O)O
Properties
Chemical formula K2HPO4
Molar mass 174.2 g/mol
Appearance white powder
deliquescent
Odor odorless
Density 2.44 g/cm
Melting point > 465 °C (869 °F; 738 K) decomposes
Solubility in water 149.25 g/100 mL (20 °C)
Solubility slightly soluble in alcohol
Acidity (pKa) 12.4
Basicity (pKb) 6.8
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1 0 0
Flash point Non-flammable
Related compounds
Other cations Disodium phosphate
Diammonium phosphate
Related compounds Monopotassium phosphate
Tripotassium phosphate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). ☒verify (what is  ?) Infobox references
Chemical compound

Dipotassium phosphate (K2HPO4) (also dipotassium hydrogen orthophosphate; potassium phosphate dibasic) is the inorganic compound with the formula K2HPO4(H2O)x (x = 0, 3, 6). Together with monopotassium phosphate (KH2PO4(H2O)x), it is often used as a fertilizer, food additive, and buffering agent. It is a white or colorless solid that is soluble in water.

It is produced commercially by partial neutralization of phosphoric acid with two equivalents of potassium chloride:

H3PO4 + 2 KCl → K2HPO4 + 2 HCl

Uses

As a food additive, dipotassium phosphate is used in imitation dairy creamers, dry powder beverages, mineral supplements, and starter cultures. It functions as an emulsifier, stabilizer and texturizer; it also is a buffering agent, and chelating agent especially for the calcium in milk products..

As a food additive, dipotassium phosphate is generally recognized as safe by the United States Food and Drug Administration, and is commonly used (in conjunction with other inorganic salts) to add taste to bottled water.

References

  1. ^ Klaus Schrödter; Gerhard Bettermann; Thomas Staffel; Friedrich Wahl; Thomas Klein; Thomas Hofmann (2012). "Phosphoric Acid and Phosphates". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a19_465.pub3. ISBN 978-3527306732.
  2. John H. Thorngate III; Seppo Salminen; Larry A. Branen; Michael P. Davidson, eds. (2001). "Food Phosphates". Food Additives. Food Science and Technology. Vol. 116. CRC Press. doi:10.1201/9780824741709.ch25 (inactive 2024-11-11). ISBN 978-0-8247-9343-2.{{cite book}}: CS1 maint: DOI inactive as of November 2024 (link)
  3. "What is dipotassium phosphate?". 30 April 2018. Retrieved 2020-09-09.
  4. "Database of Select Committee on GRAS Substances (SCOGS) Reviews". Archived from the original on 2007-05-21. Retrieved 2008-03-22. (listed as "potassium phosphate, dibasic")
  5. "Brands Of Bottled Water With Electrolytes (Confirmed By Lab Tests) - Water Purification Guide".
Phosphates
H3PO4

He
Li3PO4 Be BPO4
+BO3
C (NH4)3PO4
(NH4)2HPO4
NH4H2PO4
-N
O +F Ne
Na3PO4
Na2HPO4
NaH2PO4
Mg3(PO4)2 AlPO4 Si P +SO4
-S
Cl Ar
K3PO4
K2HPO4
KH2PO4
Ca3(PO4)2 ScPO4 Ti VPO4 CrPO4 Mn3(PO4)2
MnPO4
Fe3(PO4)2
FePO4
Co3(PO4)2 Ni3(PO4)2 Cu3(PO4)2 Zn3(PO4)2 GaPO4 Ge As -Se Br Kr
Rb3PO4 Sr3(PO4)2 YPO4 Zr3(PO4)4 Nb Mo Tc Ru Rh Pd Ag3PO4 Cd3(PO4)2 InPO4 Sn SbPO4
-SbO4
Te I Xe
Cs3PO4 Ba3(PO4)2 * LuPO4 Hf Ta W Re Os Ir Pt AuPO4 Hg Tl3PO4 Pb3(PO4)2 BiPO4 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaPO4 CePO4 PrPO4 NdPO4 PmPO4 SmPO4 EuPO4 GdPO4 TbPO4 DyPO4 HoPO4 ErPO4 TmPO4 YbPO4
** AcPO4 Th3(PO4)4 Pa U(PO4)2 Np PuPO4 AmPO4 CmPO4 Bk Cf Es Fm Md No
Potassium compounds
H, (pseudo)halogens
chalcogens
pnictogens
B, C group
transition metals
organic


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