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Lanthanum(III) iodate

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Lanthanum(III) iodate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.187 Edit this at Wikidata
EC Number
  • 237-621-3
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/3HIO3.La/c3*2-1(3)4;/h3*(H,2,3,4);/q;;;+3/p-3Key: BULVJAIIOVREOT-UHFFFAOYSA-K
SMILES
  • I(=O)=O.I(=O)=O.I(=O)=O.
Properties
Chemical formula La(IO3)3
Molar mass 663.617
Appearance colourless crystals
Solubility in water 1.07×10mol·L
Related compounds
Other anions lanthanum(III) nitrate
lanthanum(III) oxide
Other cations cerium(III) iodate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Lanthanum(III) iodate is an inorganic compound with the chemical formula La(IO3)3.

Preparation

Lanthanum(III) iodate can be obtained by reacting a La salt with potassium iodate or ammonium iodate and precipitating it:

La + 3 IO3 → La(IO3)3

Properties

Lanthanum(III) iodate can disproportionate and decompose to a periodate when heated:

10 La(IO3)3 → 2 La5(IO6)3 + 12 I2↑ + 27 O2

References

  1. ^ 《无机化学丛书》. 第七卷 钪 稀土元素. 易宪武 等主编. 科学出版社. P184~185. 13. 卤素含氧酸盐
  2. K. Nassau, J.W. Shiever, B.E. Prescott (Jun 1975). "Transition metal iodates. VI. Preparation and characterization of the larger lanthanide iodates". Journal of Solid State Chemistry. 14 (2): 122–132. Bibcode:1975JSSCh..14..122N. doi:10.1016/0022-4596(75)90002-X. Archived from the original on 2018-07-01. Retrieved 2020-05-29.{{cite journal}}: CS1 maint: multiple names: authors list (link)
Lanthanum compounds
Iodates
HIO3 He
LiIO3 Be +BO3 C (NH4)IO3
+NO3
O +F
-F
Ne
NaIO3 Mg(IO3)2 Al(IO3)3 Si P +SO4 Cl Ar
KIO3 Ca(IO3)2 Sc(IO3)3 Ti(IO3)4 V Cr Mn(IO3)2 Fe(IO3)2
Fe(IO3)3
Co(IO3)2 Ni(IO3)2 Cu(IO3)2 Zn(IO3)2 Ga(IO3)3 Ge As Se Br Kr
RbIO3 Sr(IO3)2 Y(IO3)3 Zr(IO3)4 Nb Mo Tc Ru Rh Pd AgIO3 Cd(IO3)2 In(IO3)3 Sn(IO3)4 Sb Te I Xe
CsIO3 Ba(IO3)2 * Lu(IO3)3 Hf(IO3)4 Ta W Re Os Ir Pt Au(IO3)3 Hg2(IO3)2
Hg(IO3)2
TlIO3 Pb(IO3)2 Bi(IO3)3 Po At Rn
Fr Ra(IO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(IO3)3 Ce(IO3)3 Pr(IO3)3 Nd(IO3)3 Pm(IO3)3 Sm(IO3)3 Eu(IO3)3 Gd(IO3)3 Tb(IO3)3 Dy(IO3)3 Ho(IO3)3 Er(IO3)3 Tm(IO3)3 Yb(IO3)3
** Ac Th(IO3)4 Pa U(IO3)2 Np(IO3)4 Pu(IO3)4 Am Cm Bk Cf Es Fm Md No
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