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Thulium iodate

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Thulium iodate
Identifiers
CAS Number
3D model (JSmol)
CompTox Dashboard (EPA)
InChI
  • InChI=1S/3HIO3.Tm/c3*2-1(3)4;/h3*(H,2,3,4);/q;;;+3/p-3Key: BSUUCDACXQTNMW-UHFFFAOYSA-K
SMILES
  • .O=I(=O).O=I(=O).O=I(=O)
Properties
Chemical formula Tm(IO3)3
Molar mass 693.64
Appearance gray-white
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Thulium iodate is an inorganic compound with the chemical formula Tm(IO3)3. It can be prepared by the hydrothermal reaction of periodic acid and thulium periodate in water at 160 °C. Its crystals can also be crystallized in boiling nitric acid. Its solubility in water at 25 °C is 1.467±0.001 10 mol·dm). Adding dimethyl sulfoxide to water will reduce the solubility.

References

  1. ^ Douglas, Paul; Hector, Andrew L.; Levason, William; Light, Mark E.; Matthews, Melissa L.; Webster, Michael (Mar 2004). "Hydrothermal Synthesis of Rare Earth Iodates from the Corresponding Periodates: II 1) . Synthesis and Structures of Ln(IO 3 ) 3 (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er) and Ln(IO 3 ) 3 · 2H 2 O (Ln = Eu, Gd, Dy, Er, Tm, Yb)". Zeitschrift für anorganische und allgemeine Chemie. 630 (3): 479–483. doi:10.1002/zaac.200300377. ISSN 0044-2313.
  2. Abrahams, S.C.; Bernstein, J.L.; Nassau, K. (Jan 1976). "Transition metal iodates. VII. Crystallographic and nonlinear optic survey of the 4f-iodates". Journal of Solid State Chemistry. 16 (1–2): 173–184. Bibcode:1976JSSCh..16..173A. doi:10.1016/0022-4596(76)90020-7.
  3. Miyamoto, Hiroshi; Iijima, Hiroko; Sugawara, Masako (1986-10-01). "Solubilities and Free Energies of Transfer for Lanthanoid Iodates in Dimethyl Sulfoxide–Water Mixtures". Bulletin of the Chemical Society of Japan. 59 (10): 2973–2978. doi:10.1246/bcsj.59.2973. ISSN 0009-2673.
Thulium compounds
Tm(II)
Tm(III)
Iodates
HIO3 He
LiIO3 Be +BO3 C (NH4)IO3
+NO3
O +F
-F
Ne
NaIO3 Mg(IO3)2 Al(IO3)3 Si P +SO4 Cl Ar
KIO3 Ca(IO3)2 Sc(IO3)3 Ti(IO3)4 V Cr Mn(IO3)2 Fe(IO3)2
Fe(IO3)3
Co(IO3)2 Ni(IO3)2 Cu(IO3)2 Zn(IO3)2 Ga(IO3)3 Ge As Se Br Kr
RbIO3 Sr(IO3)2 Y(IO3)3 Zr(IO3)4 Nb Mo Tc Ru Rh Pd AgIO3 Cd(IO3)2 In(IO3)3 Sn(IO3)4 Sb Te I Xe
CsIO3 Ba(IO3)2 * Lu(IO3)3 Hf(IO3)4 Ta W Re Os Ir Pt Au(IO3)3 Hg2(IO3)2
Hg(IO3)2
TlIO3 Pb(IO3)2 Bi(IO3)3 Po At Rn
Fr Ra(IO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(IO3)3 Ce(IO3)3 Pr(IO3)3 Nd(IO3)3 Pm(IO3)3 Sm(IO3)3 Eu(IO3)3 Gd(IO3)3 Tb(IO3)3 Dy(IO3)3 Ho(IO3)3 Er(IO3)3 Tm(IO3)3 Yb(IO3)3
** Ac Th(IO3)4 Pa U(IO3)2 Np(IO3)4 Pu(IO3)4 Am Cm Bk Cf Es Fm Md No
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