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Terbium(III) iodate

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Terbium(III) iodate
Identifiers
CAS Number
3D model (JSmol)
EC Number
  • 238-793-2
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/3HIO3.Tb/c3*2-1(3)4;/h3*(H,2,3,4);/q;;;+3/p-3Key: BQNHJSVUMZSXKE-UHFFFAOYSA-K
SMILES
  • I(=O)=O.I(=O)=O.I(=O)=O.
Properties
Chemical formula Tb(IO3)3
Molar mass 683.63
Density 5.735 g·cm
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Terbium(III) iodate is an inorganic compound with the chemical formula Tb(IO3)3. It can be obtained by the reaction of terbium(III) periodate and periodic acid in water at 160 °C, or by the hydrothermal reaction of terbium(III) nitrate or terbium(III) chloride and iodic acid at 200 °C . It crystallizes in the monoclinic crystal system, with space group P21/c and unit cell parameters a=7.102, b=8.468, c=13.355 Å, β=99.67°.

References

  1. ^ Douglas, Paul; Hector, Andrew L.; Levason, William; Light, Mark E.; Matthews, Melissa L.; Webster, Michael (Mar 2004). "Hydrothermal Synthesis of Rare Earth Iodates from the Corresponding Periodates: II 1) . Synthesis and Structures of Ln(IO 3 ) 3 (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er) and Ln(IO 3 ) 3 · 2H 2 O (Ln = Eu, Gd, Dy, Er, Tm, Yb)". Zeitschrift für anorganische und allgemeine Chemie. 630 (3): 479–483. doi:10.1002/zaac.200300377. ISSN 0044-2313.
  2. Phanon, Delphine; Mosset, Alain; Gautier-Luneau, Isabelle (Jun 2007). "New iodate materials as potential laser matrices. Preparation and characterisation of α-M(IO3)3 (M=Y, Dy) and β-M(IO3)3 (M=Y, Ce, Pr, Nd, Eu, Gd, Tb, Dy, Ho, Er). Structural evolution as a function of the Ln3+ cationic radius". Solid State Sciences. 9 (6): 496–505. doi:10.1016/j.solidstatesciences.2007.04.004.
Terbium compounds
Terbium(III)
Terbium(III,IV)
Terbium(IV)
Iodates
HIO3 He
LiIO3 Be +BO3 C (NH4)IO3
+NO3
O +F
-F
Ne
NaIO3 Mg(IO3)2 Al(IO3)3 Si P +SO4 Cl Ar
KIO3 Ca(IO3)2 Sc(IO3)3 Ti(IO3)4 V Cr Mn(IO3)2 Fe(IO3)2
Fe(IO3)3
Co(IO3)2 Ni(IO3)2 Cu(IO3)2 Zn(IO3)2 Ga(IO3)3 Ge As Se Br Kr
RbIO3 Sr(IO3)2 Y(IO3)3 Zr(IO3)4 Nb Mo Tc Ru Rh Pd AgIO3 Cd(IO3)2 In(IO3)3 Sn(IO3)4 Sb Te I Xe
CsIO3 Ba(IO3)2 * Lu(IO3)3 Hf(IO3)4 Ta W Re Os Ir Pt Au(IO3)3 Hg2(IO3)2
Hg(IO3)2
TlIO3 Pb(IO3)2 Bi(IO3)3 Po At Rn
Fr Ra(IO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(IO3)3 Ce(IO3)3 Pr(IO3)3 Nd(IO3)3 Pm(IO3)3 Sm(IO3)3 Eu(IO3)3 Gd(IO3)3 Tb(IO3)3 Dy(IO3)3 Ho(IO3)3 Er(IO3)3 Tm(IO3)3 Yb(IO3)3
** Ac Th(IO3)4 Pa U(IO3)2 Np(IO3)4 Pu(IO3)4 Am Cm Bk Cf Es Fm Md No
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